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• 试剂商城
• 直接询价

分类

• Amber Glass Bottles, Building Blocks, C2 to C8, Chemical Synthesis, Ethers,
• {Chemicalbook} 食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香料
• {SNA} A - D, A-B, A-D, Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances, Follows IFRA Guidelines, Halal Certified Products, Kosher Certified Products
• {SNA} A-B, A-F, Additional Standards, Alpha Sort, Analytical Standards,
• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment
• {SNA} Anhydrous Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents, Sure/Seal Bottles
• {SNA} Amber Glass Bottles,

产品应用

• A biochemical for proteomics research.

相关文献及参考

• Merck:14,669 Beilstein:6(4)548
• The rate of ortho-lithiation of anisole is accelerated dramatically in the presence of TMEDA, effective also in sub-stoichiometric amounts: Tetrahedron Lett., 35, 385 (1994). For discussion of the mechanism of ortho-lithiation, see: J. Org. Chem., 62, 3024 (1997). Although direct dilithiation with n-BuLi/TMEDA was unsuccessful, a sequence involving monolithiation, silylation and further lithiation at the 6-position gave the 2,6-disilyl derivative in 72% yield: J. Org. Chem., 49, 4657 (1984).
• Merck:14,669
• Short: II/19b
• Widely used as a carbocation scavenger in the deblocking of, e.g. N-Boc or N-Cbz (Z) peptides with acidic reagents. Addition of anisole removes t-butyl or benzyl cations from the reaction mixture; see, e.g.: J. Chem. Soc., Chem. Commun., 922 (1976); Chem. Pharm. Bull., 25, 2929 (1977); Chem. Ber., 101, 3649 (1968).

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3700 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   6,378,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2800 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - excitement
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 88,400,1946

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5000 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(6),43,1984

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 25 umol/L
REFERENCE :
   RCOCB8 Research Communications in Chemical Pathology and Pharmacology. (PJD
   Pub. Ltd., P.O. Box 966, Westbury, NY 11590)  V.1-    1970-
   Volume(issue)/page/year: 54,133,1986

其他信息

• 下游产品:1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 头孢地尼 --> 1,5-二氮杂双环[4.3.0]壬-5-烯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 诱惑红 --> 敌菌净 --> 头孢布烯 --> 2-肼基甲基吡啶 --> 1H-咪唑-4-甲酸 --> 甲基多巴 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 吡啶-3-亚甲基肼,1-(3-吡啶基)甲基肼 --> 劳森试剂 --> 6-羟基-1-萘甲酸 --> 分散兰BGL --> 1-[4-(4-氨基-6,7-二甲氧基喹唑啉-2-基)-1,4-二氮杂环庚烷-1-基]丁-1-酮盐酸盐 --> 跟踪,示踪,微量 --> 间-油酰氨基-邻-甲氧基苯磺酸钠,净洗剂MA,洗净剂SL -
• 用途四:用于有机合成，也用作溶剂、香料和驱虫剂。
• {
• 毒性分级:中毒
• {Chemical
• 常规方法:用铁桶内衬塑料袋包装。每桶净重100kg。贮存于阴凉、通风处。防潮、防晒。按有毒化学品规定贮运。
• 图谱信息:苯甲醚(100-66-3)红外图谱(IR2) 苯甲醚(100-66-3)核磁图( 13 CNMR) 苯甲醚(100-66-3)质谱(MS) 苯甲醚(100-66-3)Ram
• Acros Organics:苯甲醚 Anisole, extra pur
• 下游产品:1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 头孢地尼 --> 1,5-二氮杂双环[4.3.0]壬-5-烯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 诱惑红 --> 敌菌净 --> 头孢布烯 --> 2-肼基甲基吡啶 --> 1H-咪唑-4-甲酸 --> 甲基多巴 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 吡啶-3-亚甲基肼,1
• TCI Shanghai:苯甲醚 Anisole,>;99.0%(GC)(100-66-3)
• 职业标准:STEL 10 毫克/ 立方米
• 蒸气压:10 mm Hg ( 42.2 °C)
• 蒸气密度:3.7 (vs air)
• {Ch
• 下游产品:1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 头孢地尼 --> 1,5-二氮杂双环[4.3.0]壬-5-烯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 诱惑红 --> 敌菌净 --> 头孢布烯 --> 2-肼基甲基吡啶 --> 1H-咪唑-4-甲酸 --> 甲基多巴 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 吡啶-3-亚甲基肼,1-(3-吡啶基)甲基肼 --> 劳森试剂 --> 6-羟基-1-萘甲酸 --> 分散兰BGL --> 1-[4-(4-氨基-6,7-二甲氧基喹唑啉-2-基)-1,4-二氮杂环庚烷-1-基]丁-1-酮盐酸盐 --> 跟踪,示踪,微量 --> 间-油酰氨基-邻-甲氧基苯磺酸钠,净洗剂MA,洗净剂SL --> 头孢卡品酯 --> 维拉帕米 --> 6-甲氧基萘甲酸 --> 阿诺克索牟抗氧剂
• 用途三:GB 2760—1996规定为允许使用的食品用香料。主要用于配制香草、茴香和啤酒型香精。
• 使用限量:FEMA(mg/kg)：软饮料9.0；冷饮16；糖果51；焙烤食品34。 以适度为限(FDA§172．515，2000)。
• 上游原料:氢氧化钠 --> 硫酸二甲酯 --> 苯酚 --> 二甲酯 --> 二甲醚
• 防护
• 参考质量标准:FCC，1996 馏程 154℃士2℃ 折射率(n D 20 ) 1.515～1.518 相对密度(d 25 25 ) 0.990～0.993 酚类试验 阴性
• 可燃性危险特性:遇明火、高温、强氧化剂可燃；燃烧排放刺激烟雾
• 急性毒性:口服- 大鼠 L
• 检测方法:GC