3,3'-Dimethoxybenzidine 3,3-二甲氧基联苯胺

CAS 119-90-4 MFCD00008372

化学结构图

119-90-4
SMILES: COc1cc(-c2ccc(N)c(OC)c2)ccc1N

化学属性

Mol. FormulaC₁₄H₁₆N₂O₂
Mol. Weight244.28
Melting Point>130°C (dec.)
Flash Point-
TSCAYes
Density1.422
Stability对光敏感
SolubilityH2O: slightly soluble
Boiling Point

别名和识别编码

Chemical Name3,3'-Dimethoxybenzidine
Synonym 1’-Biphenyl)-4,4’-diamine,3,3’-dimethoxy-(1 3'-二甲氧基联苯胺 3,3' Dimethoxybenzidine 3,3'-Dimethoxybenzidine 3,3’-dianisidine 3,3’-dimethoxy-benzidin 3,3’-dimethoxybiphenyl-4,4’-diamine 3,3’-二甲氧基-4,4’-二氨基联苯 3,3’-二甲氧基联苯胺 3,3′-Dimethoxybenzidine, Fast Blue B 4,4'-Diamino-3,3'-dimethoxybiphenyl Acetamine Diazo Navy RD Azogene Fast Blue B C.I. Disperse Black 6 Diacel Navy DC Diacelliton Fast Grey G Dianisidine Dianisidine Dihydrochloride Dianisidine Hydrochloride Dianisidine Sulfate Dihydrochloride, Dianisidine FAST BLUE B FAST BLUE B BASE Hiltonil Fast Blue B Base Hydrochloride, Dianisidine O Dianisidine O-DIANISIDINE O-Dianisidine {PubChe
CAS Number119-90-4
PubChem Substance ID8411
EC Number204-355-4
Beilstein Registry Number13(4)2834
MDL Number-
Reaxys-RN1879884
Merck Number2991
Chemical Name Translation3,3-二甲氧基联苯胺
Wiswesser Line Notation1OR BZ ER DZ CO1
LabNetwork Molecule IDLN00194432
InChIInChI=1S/C14H16N2O2/c1-17-13-7-9(3-5-11(13)15)10-4-6-12(16)14(8-10)18-2/h3-8H,15-16H2,1-2H3
Canonical SMILES-
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分类

  • Aldehydes/Ketones, Analytical Reagents, Analytical Standards, Analytical/Chromatography, Biochemicals and Reagents, Chromatography, Cyanates & Cyanide, Derivatization Reagents, Derivatization Reagents TLC, Fluorescent Enzyme Substrates, Fluorescent Enzyme Substrates for Immunoassays, Fluorescent Probes, Labels, Particles and Stains, Food & Beverage Standards, Food Dyes, Food Residue Analysis, Metal Ions, Metals, precious, Nitrogen-containing compounds, Spectroscopy, TLC Reagents, D-F, TLC Visualization Reagents (alphabetic sort), TLC Visualization Reagents (by application), UV/Vis Reagents,
  • {SNA} Alphabetical Listing,
  • {SNA} Aldehydes

产品应用

  • 检定钴、铜、金、钒、硫氰酸盐(Au, Co, Cu, SCN-, V),测定金和亚硝酸盐(Au, NO2-, Ce(IV) )(spectrophotometric)。氧化还原指示剂。络合指示剂。偶氮染料制造。

相关文献及参考

  • Merck: 14,2991
  • Merck: 14,2991 Beilstein: 13,IV,2834
  • Redox indicator.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Gloves, type P2 (EN 143) respirator cartridges Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSDD0875000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+
  • P301+P312+P330
  • P301+P317
  • P305+P351+P338
  • P308+P311
  • P308+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P318
  • P319
  • P330 Rinse mouth. 漱口
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number 3077 2811
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Storage condition -20 -20°C, Inert atmosphere Store at RT. 产品在储存期间颜色会变暗,密封避光保存。 充氩保存
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - hamster
DOSE/DURATION           : 588 gm/kg/70W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   PAACA3 Proceedings of the American Association for Cancer Research. (Waverly
   Press, 428 E. Preston St., Baltimore, MD 21202)  V.1-    1954-
   Volume(issue)/page/year: 10,78,1969

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 12 gm/kg/56W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Sense Organs and Special Senses (Ear) - effect, not otherwise specified
   Skin and Appendages - tumors
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 9(7),18,1965

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie.  (Leipzig,
   Ger. Dem. Rep.)  V.1-109, 1873-1925.  For publisher information, see NSAPCC.
    Volume(issue)/page/year: 58,167,1907

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1920 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,723,1986

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 500 umol/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 3,11,1981

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 500 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 100 nmol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   38,2621,1978

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MDMIAZ Medycyna Doswiadczalna i Mikrobiologia.  For English translation, see
   EXMMAV.  (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland)  V.1-    1949-
   Volume(issue)/page/year: 31,

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Mammal - dog Cells - not otherwise specified
DOSE/DURATION           : 100 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   44,1893,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1)

其他信息

  • TCI Shanghai:3,3'-二甲氧基联苯胺 o-Dianisidine,>;95.0%(T)(119-90-4)
  • 急性毒性:口服- 大鼠 LD50: 1920 毫克/ 公斤
  • 毒性分级:中毒
  • 可燃性危险特性:明火、高热可燃; 与氧化剂反应;燃烧产生有毒氮氧化物烟雾
  • 用途二:用作分析试剂、氧化还原指示剂、吸附指示剂及检验铁的络合指示剂
  • 色指数:37235
  • 在空气中变成紫堇色。溶于乙醇、乙醚和苯,几乎溶于水。低毒,半数致死量(大鼠,经口)1920mg/kg。有致癌可能性。有刺激性。
  • MOL 文件:119-90-4.mol
  • MSDS 信息:邻甲氧基联苯胺(119-90-4).msds
  • 联大茴香胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K3343002 3,3’-二甲氧基联苯胺 50g 1657元 2011/04/16 D3864 邻联茴香胺[用于生化研究] o-Dianisidine [for Biochemical Research] 1G 208元 2011/04/16 D3864 邻联茴香胺[用于生化研究] o-Dianisidine [for Biochemical Research] 5G 623元
  • Alfa Aesar:邻联茴香胺,98+% o-Dianisidine, 98+%(119-90-4)
  • 用途一:用作颜料中间体
  • 用途三:检定钴、铜、金、钒、硫氰酸盐(Au, Co, Cu, SCN-, V),测定金和亚硝酸盐(Au, NO2-, Ce(IV) )(spectrophotometric)。氧化还原指示剂。络合指示剂。偶氮染料制造。
  • 下游产品:3,3'-二羟基联苯胺 --> 直接兰151 --> 直接铜蓝 2R --> 滂胺天蓝
  • 类别:有毒物品
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 外观性质:棕褐色粉末。
  • 灭火剂:泡沫、二氧化碳、雾状水、干粉
  • Sigma Aldrich:119-90-4(sigmaaldrich)
  • 图谱信息:联大茴香胺(119-90-4)核磁图( 13 CNMR) 联大茴香胺(119-90-4)红外图谱(IR1) 联大茴香胺(119-90-4)质谱(MS) 联大茴香胺(119-90-4)红外图谱(IR2)
  • Acros Organics:3,3'-二甲氧基联苯胺/邻二茴香胺 3,3'-Dimethoxybenzidine, 97%(119-90-4)

系列性分类


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