1,1,3,3-Tetramethoxypropane 1,1,3,3-四甲氧基丙烷

CAS 102-52-3 MFCD00008488

化学结构图

102-52-3
SMILES: COC(CC(OC)OC)OC

化学属性

Mol. FormulaC7H16O4
Mol. Weight164.20
Density0.997
Boiling Point183°C at 760 mmHg
Refractive index1.4060 to 1.4090
Flash Point54°C
TSCAYes
SolubilitySoluble in ether, hexane, and alcohol. Insoluble in water.
Stability对湿度敏感

别名和识别编码

Chemical Name1,1,3,3-Tetramethoxypropane
CAS Number102-52-3
EC Number203-037-2
Beilstein Registry Number1700020
MDL NumberMFCD00008488
Synonym Tetramethoxypropane {LY} Tetramethoxypropane {} {LY} Tetramethoxypropane {} {} {LY} Tetramethoxypropane {} {} {} {LY} Tetramethoxypropane {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethoxypropane {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID135727155
Reaxys-RN1700020
Chemical Name Translation1,1,3,3-四甲氧基丙烷
InChIKeyXHTYQFMRBQUCPX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225817
InChIInChI=1S/C7H16O4/c1-8-6(9-2)5-7(10-3)11-4/h6-7H,5H2,1-4H3
Canonical SMILESCOC(OC)CC(OC)OC
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

产品应用

  • Usually used in preparing malondialdehyde standards during malondialdehyde assay on lung homogenates,and also used to study the effect of Salvianolic acid A on the migration and proliferation of vascular smooth muscle cells.

相关文献及参考

  • Beilstein:1(3)3095
  • Malonaldehyde source in the synthesis of a number of heterocyclic systems. For use in the synthesis of pyrimidine N-oxides, see: Tetrahedon Lett., 33, 2195 (1992). For conversion to malonaldehyde monoacetals, see: Liebigs Ann. Chem., 1045 (1989).

安全信息

Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Packing GroupIII
UN Number 1993 UN3271
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 3
Hazard Class3

其他信息

  • 检测方法:GC
  • Hazard Note:Irritant
  • 海关编码:29110000
  • 下游产品:2-氨基-5-溴烟酸 --> 2-乙酰氨基-吡啶-3-羧酸 --> 1H-吡唑基[3,4-B]吡啶-3-羧酸 --> 2-溴丙二醛 --> 3-甲基-5-硝基-1H-吡唑[3,4B]吡啶 --> 3-氨基-1H-吡唑并[3,4-b]吡啶 --> 1-苯基-1H-吡唑-4-甲醛 --> 3-溴-1H-吡唑并[3,4B]吡啶 --> 2-氨基烟酸 --> 2-氨基-3-氰基吡啶 --> 3-甲基-1H-吡唑并[3,4-B]吡啶 --> 3-(1H-吡咯-1-基)苯甲酸 --> 1H-吡唑并[3,4-B]吡啶 --> 1-苯基吡唑
  • 1,1,3,3-Tetramethoxypropane is a precursor of malondialdehyde and a naturally occurring product of lipid peroxidation and prostaglandin biosynthesis, which is formed by oxidation of polyunsaturated fatty acids in foods. It can be mutagenic or carcinogenic due to its reaction with DNA creating adducts of deoxyguanosine and deoxyadenosine.
  • TCI Shanghai:1,1,3,3-四甲氧基丙烷 1,1,3,3-Tetramethoxypropane,>;98.0%(GC)(102-52-3)
  • 方法一:由丙酮醛缩二甲醇通过电解法制备
  • 外观:无色透明液体
  • MOL 文件:102-52-3.mol
  • 1,1,3,3-四甲氧基丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0544 1,1,3,3-四甲氧基丙烷 1,1,3,3-Tetramethoxypropane 500G 688元 2014/06/02 M0544 1,1,3,3-四甲氧基丙烷 1,1,3,3-Tetramethoxypropane 25G 124元 2010/06/21 148615000 1,1,3,3-四甲氧基丙烷 Malonaldehyde bis(dimethyl acetal) 99+% 500 GR 896元
  • 不溶于水。溶于己烷,醚和醇。
  • Alfa Aesar:1,1,3,3-四甲氧基环丙烷,99% 1,1,3,3-Tetramethoxypropane, 99%(102-52-3)
  • 比重:0.919g/cm3
  • MSDS 信息:1,1,3,3-Tetramethoxypropane(102-52-3).msds
  • F:21
  • 用途二:制备3-乙磺酰基-2-吡啶磺酰胺的原料药
  • 存储注意事项:湿度敏感
  • 图谱信息:1,1,3,3-四甲氧基丙烷(102-52-3)质谱(MS) 1,1,3,3-四甲氧基丙烷(102-52-3)核磁图( 13 CNMR) 1,1,3,3-四甲氧基丙烷(102-52-3)Raman光谱 1,1,3,3-四甲氧基丙烷(102-52-3)红外图谱(IR1) 1,1,3,3-四甲氧基丙烷(102-52-3)核磁图( 1 HNMR) 1,1,3,3-四甲氧基丙烷(102-52-3)红外图谱(IR2)
  • 用途一:用作医药和染料中间体,也可以作为农产品保鲜剂的中间体
  • Sigma Aldrich:102-52-3(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • Acros Organics:1.1.3.3.-四甲氧基丙烷 Malonaldehyde bis(dimethyl acetal), 99+%(102-52-3)

系列性分类