Tri-p-tolylphosphine 三(对甲苯基)膦

CAS 1038-95-5 MFCD00008542

化学结构图

1038-95-5
SMILES: Cc1ccc(P(c2ccc(C)cc2)c2ccc(C)cc2)cc1

化学属性

Density1.422
TSCAYes
Mol. FormulaC21H21P
Mol. Weight304.37
Appearance white xtl.
Stabilityair sensitive
Melting Point144-146°C
Boiling Point399.8°C at 760 mmHg
Flash Point206.3°C

别名和识别编码

Chemical NameTri(p-tolyl)phosphine
Synonym Tri-p-tolylphosphine {LY} Tri-p-tolylphosphine {} {LY} Tri-p-tolylphosphine {} {} {LY} Tri-p-tolylphosphine {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {}
EC Number213-863-5
Beilstein Registry Number651045
PubChem Substance ID13956
Reaxys-RN651045
Chemical Name Translation三(对甲苯基)膦
Wiswesser Line Notation1R DPR D1&R D1
InChIKeyWXAZIUYTQHYBFW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00226948
InChIInChI=1S/C21H21P/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21/h4-15H,1-3H3
MDL NumberMFCD00008542
CAS Number1038-95-5
Canonical SMILESCC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/35C4
  • Beilstein: 16,IV,959
  • Short: EINECS

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSSZ3880000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under
Hazard Codes Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02043

其他信息

  • 三对苯甲基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0862 三(4-甲基苯基)膦 Tris(4-methylphenyl)phosphine 5G 596元 2014/06/02 T0862 三(4-甲基苯基)膦 Tris(4-methylphenyl)phosphine 25G 1590元 2010/06/21 422330010 三对苯甲基膦 Tri-p-tolylphosphine 95% 1 GR 354元
  • Acros Organics:三对甲苯基膦 Tri-p-tolylphosphine, 95%(1038-95-5)
  • 敏感性:Air Sensitive
  • MOL 文件:1038-95-5.mol
  • TCI Shanghai:三(4-甲基苯基)膦 Tris(4-methylphenyl)phosphine,>;95.0%(GC)(T)(1038-95-5)
  • F:10-23
  • 图谱信息:三对苯甲基膦(1038-95-5)红外图谱(IR1) 三对苯甲基膦(1038-95-5)质谱(MS) 三对苯甲基膦(1038-95-5)核磁图( 1 HNMR) 三对苯甲基膦(1038-95-5)核磁图( 13 CNMR) 三对苯甲基膦(1038-95-5)红外图谱(IR2)
  • Alfa Aesar:三(对甲苯基)膦,98% Tri(p-tolyl)phosphine, 98%(1038-95-5)
  • Sigma Aldrich:1038-95-5(sigmaaldrich)
  • 检测方法:HPLC,NMR
  • 上游原料:乙醇 --> 盐酸 --> 乙酸乙酯 --> 四氢呋喃 --> 二氯甲烷 --> 石油醚 --> 镁 --> 三氯化磷 --> 对溴甲苯 --> 3,5-二甲基溴苯
  • 存储注意事项:空气敏感

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Basic Phosphine Ligands - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus