4-Methylstyrene 4-甲基苯乙烯

CAS 622-97-9 MFCD00008621

化学结构图

622-97-9
SMILES:

化学属性

Mol. FormulaC₉H₁₀
Mol. Weight118.18
Refractive index1.5410 to 1.5450
Boiling Point-
Density0.896
Flash Point-
TSCAYes
Melting Point-34
Autoignition Point959 °F
Vapor Pressure<;1 mmHg ( 20 °C)
Solubility不溶于水,溶于乙醇、乙醚。

别名和识别编码

Chemical Name4-Methylstyrene
Synonym 1-Ethenyl-4-methylbenzene 1-ethenyl-4-methyl-Benzene 1-methyl-4-ethenylbenzene 1-甲基-4-乙烯基苯 4-Methylphenylene 4-Methylsytrene (stabilized with TBC) {Chemicalbook} VINYLTOLUENE p-Methylphenylene p-Methylstyrene p-methyl-styren styrene,p-methyl- {} {Chemicalbook} PARA-METHYLSTYRENE {} {} {SNA} 4-甲基苯乙烯 {} {} {} {SNA} 4-乙烯基甲苯
CAS Number622-97-9
PubChem Substance ID87572487
EC Number210-762-8
Beilstein Registry Number5,485
MDL Number-
Chemical Name Translation4-甲基苯乙烯
Reaxys-RN1209317
Wiswesser Line Notation1U1R D1
LabNetwork Molecule IDLN00221758
Canonical SMILES-
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分类

  • {SNA} Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers, 材料科学
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Monomers, Organic Building Blocks, Polymer Science, Styrene and Functionalized Styrene Monomers, 材料科学
  • Materials Science, Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Materials Science, Monomers, Organic Building Blocks, Polymer Science, Styrene and Functionalized Styrene Monomers

相关文献及参考

  • Beil. 5 ,IV,1369
  • Aldrich MSDS 1 , 1307:A / Corp MSDS 1 (2), 2438:D / FT-IR 1 (1), 947:B / FT-IR 2 (2), 1647:A / FT-NMR 1 (2), 27:A / IR-Spectra (2), 508:F / IR-Spectra (3), 570:H / RegBook 1 (1), 1139:N / Sax 6 , 1929 / Structure Index 1 , 176:D:1 / Vapor Phase 3 , 869:C

安全信息

GHS Symbol
WGK Germany3
Hazard Codes
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSWL5076000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
  • P303+P361+P353
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P302+P352+P332+P313+P362+P364
  • P241+P242+P243
  • P403+P235
Signal word Danger
Packing GroupIII
UN Number UN2618 2618
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Storage condition 0-10 0-10°C 2-8°C 4°C, Inert atmosphere, Light sensitive
Hazard Class3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2255 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Lungs, Thorax, or Respiration - respiratory depression
   Gastrointestinal - other changes
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,77,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2324 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Lungs, Thorax, or Respiration - respiratory depression
   Gastrointestinal - other changes
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,77,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Gastrointestinal - nausea or vomiting
   Gastrointestinal - changes in structure or function of salivary glands
   Behavioral

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 581 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,76,1990

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 330 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 2,237,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 330 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 2,237,1981

其他信息

  • 4-甲基苯乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0428 4-甲基苯乙烯(含稳定剂TBC) 4-Methylstyrene (stabilized with TBC) 25ML 175元 2014/06/02 M0428 4-甲基苯乙烯(含稳定剂TBC) 4-Methylstyrene (stabilized with TBC) 500ML 1540元 2010/06/21 127701000 4-甲基苯乙烯 p-Methylstyrene 98%, stabilized 100 ML 589元
  • 毒性分级:中度
  • 海关编码:29029050
  • 职业标准:TWA 120 毫克/ 立方米
  • 可燃性危险特性:明火、受热、氧化剂可燃;燃烧排放刺激烟雾
  • 灭火剂:雾状水、泡沫、砂土、二氧化碳、1211灭火剂
  • Acros Organics:4-甲基苯乙烯/对甲基苯乙烯 p-Methylstyrene, stabilized, 98%(622-97-9)
  • MOL 文件:622-97-9.mol
  • 急性毒性:口服- 小鼠 LD50: 2255 毫克/ 公斤; 口服- 小鼠 LD50: 1072 毫克/ 公斤
  • Alfa Aesar:对甲基苯乙烯,98+%,、0.1%3,5-二叔丁基儿茶酚作稳定剂 4-Methylstyrene, 98+%, stab. with 0.1% 3,5-di-tert-butylcatechol(622-97-9)
  • Sigma Aldrich:622-97-9(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 轻装轻卸、与氧化剂和酸类分开存放; 不易久储以防聚合
  • TCI Shanghai:4-甲基苯乙烯(含稳定剂叔丁基邻苯二酚) 4-Methylstyrene (stabilized with TBC),>;96.0%(GC)(622-97-9)
  • 外观性质:无色液体。
  • 爆炸物危险特性:与空气混合可爆
  • 图谱信息:4-甲基苯乙烯(622-97-9)核磁图( 1 HNMR) 4-甲基苯乙烯(622-97-9)质谱(MS) 4-甲基苯乙烯(622-97-9)红外图谱(IR1)
  • 蒸气压:<;1 mm Hg ( 20 °C)
  • 类别:易燃液体
  • MSDS 信息:4-甲基苯乙烯(622-97-9).msds

系列性分类


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