Diallyldisulfide 二烯丙基二硫

CAS 2179-57-9 MFCD00008656

化学结构图

2179-57-9
SMILES: C=CCSSCC=C

化学属性

Mol. FormulaC6H10S2
Mol. Weight146.27
Refractive index1.5400 to 1.5450
Boiling Point180-195 °C at 760 mmHg
Density1.01
Flash Point62°C(lit.)
TSCAYes
Vapor Density>;5 (vs air)
Vapor Pressure1 mmHg ( 20 °C)
Appearance 淡黄色液体。呈大蒜特殊气味,有催泪性。沸点138~139℃,或79℃(2133Pa)。不溶于水,溶于大多数普通有机溶剂。 天然品存在于生白菜、洋葱、大蒜、细香葱等中。
Stability对热和空气敏感
Melting PointN/A

别名和识别编码

Chemical NameDiallyldisulfide
Synonym Diallyl disulfide {LY} Diallyl disulfide {} {LY} Diallyl disulfide {} {} {LY} Diallyl disulfide {} {} {} {LY} Diallyl disulfide {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number2179-57-9
PubChem Substance ID16590
EC Number218-548-6
Beilstein Registry Number1699241
MDL NumberMFCD00008656
Reaxys-RN1699241
Chemical Name Translation二烯丙基二硫
LabNetwork Molecule IDLN00162843
InChIInChI=1S/C6H10S2/c1-3-5-7-8-6-4-2/h3-4H,1-2,5-6H2
Canonical SMILESC=CCSSCC=C
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分类

  • {Chemicalbook} 食品添加剂: 食用香料(增香剂): 天然等同香料和人造香
  • {SNA} Building Blocks, Chemical Synthesis, Oils and Resin-derived, Organic Building Blocks, Phytochemicals by Chemical Classification, Sulfides/Disulfides, Sulfur Compounds, 细胞生物学, 营养研究
  • {SNA} Building Blocks, Cell Biology, Chemical Synthesis, Nutrition Research, Oils and Resin-derived, Organic Building Blocks, Phytochemicals by Chemical Classification, Sulfides/Disulfides, Sulfur Compounds
  • {SNA} A - D, A-B, A-D, Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances,

相关文献及参考

  • Beilstein: 1,IV,2098

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xn
RTECSBB1000000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2810
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupIII
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 260 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   26,297,1988

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   26,297,1988

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 8 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 mg/L
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   35,379,1997

其他信息

  • 蒸气压:1 mm Hg ( 20 °C)
  • FEMA:2028
  • 毒性:GRAS(FEMA)。
  • TCI Shanghai:二烯丙基二硫醚 Diallyl Disulfide,>;75.0%(GC)(2179-57-9)
  • Alfa Aesar:二硫化二烯丙基,tech.80% Diallyl disulfide, tech. 80%(2179-57-9)
  • 二烯丙基二硫价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0071 二烯丙基二硫醚 Diallyl Disulfide 25G 467元 2010/06/21 293320250 二烯丙基二硫 Diallyldisulfide 70%, remainder mainly diallyl sulfide 25 GR 471元 2010/06/21 293321000 二烯丙基二硫 Diallyldisulfide 70%, remainder mainly diallyl sulfide 100 GR 1272元
  • Acros Organics:二烯丙基二硫醚 Diallyldisulfide, remainder mainly diallyl sulfide, 70%(2179-57-9)
  • 用途二:食品用香料。
  • 使用限量:FEMA(mg/kg):调味品6.5;肉类7.0。 FDA,§172.515(2000):适量为限。
  • 蒸气密度:>;5 (vs air)
  • 类别:有毒物品
  • 图谱信息:二烯丙基二硫(2179-57-9)红外图谱(IR1) 二烯丙基二硫(2179-57-9)核磁图( 13 CNMR) 二烯丙基二硫(2179-57-9)质谱(MS)
  • MOL 文件:2179-57-9.mol
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • MSDS 信息:Allyl disulfide(2179-57-9).msds
  • F:13
  • 参考质量标准:FAO/WHO,1999 含量(GT-10-4) ≥80% 折射率( D 20 ) 1.537~1.551 相对密度(d 25 25 ) 0.998~1.015
  • 急性毒性:口服-大鼠LD50: 260毫克/公斤
  • 溶于乙醇、氯仿或乙醚,不溶于水。具有强烈的大蒜味,味辣。
  • Sigma Aldrich:2179-57-9(sigmaaldrich)
  • 上游原料:烯丙硫醇
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 烯丙基二硫醚 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • 毒性分级:高毒
  • 可燃性危险特性:可燃;燃烧产生有毒硫氧化物烟雾
  • 方法一:由烯丙基硫醇与碘在乙醇和吡啶存在下氧化而得。
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 用途三:广谱抗菌药。治疗消化道、呼吸道及阴道的霉菌感染,如菌痢、百日咳等均有效。
  • 用途一:用作食品添加剂、医药中间体

系列性分类


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