Aluminum tert-butoxide 叔丁醇铝

CAS 556-91-2 MFCD00008801

化学结构图

556-91-2
SMILES: CC(C)(C)O[AlH3](OC(C)(C)C)OC(C)(C)C

化学属性

Mol. FormulaC12H27AlO3
Mol. Weight246.32
Density1.0251
Melting Point241 °C
SolubilityVery soluble in organic solvents
TSCAYes
Boiling Point156 °C at 2 mmHg
Flash Point>65°C

别名和识别编码

Chemical NameAluminum tert-Butoxide
Synonym Aluminum tert-Butoxide {LY} Aluminum tert-Butoxide {} {LY} Aluminum tert-Butoxide {} {} {LY} Aluminum tert-Butoxide {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} A
Beilstein Registry Number4148229
PubChem Substance ID68399
CAS Number556-91-2
EC Number209-146-1
MDL NumberMFCD00008801
Reaxys-RN4148229
Merck Number333
Chemical Name Translation叔丁醇铝
LabNetwork Molecule IDLN01739958
InChIInChI=1S/3C4H9O.Al/c3*1-4(2,3)5;/h3*1-3H3;/q3*-1;+3
Canonical SMILESCC(C)(C)O[Al](OC(C)(C)C)OC(C)(C)C
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分类

  • {SNA} Aluminum, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SNA} Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors

相关文献及参考

  • Merck 14 ,333
  • Beil. 1 ,IV,1612
  • Fieser 1 ,23 / Fieser 2 ,21
  • Aldrich MSDS 1 , 54:A / Corp MSDS 1 (1), 116:B / FT-IR 1 (2), 1281:A / FT-IR 2 (3), 4494:D / RegBook 1 (2), 3059:E / Structure Index 1 , 484:D:9
  • Catalyst for the Oppenauer oxidation of secondary alcohols to ketones by hydride transfer, normally to acetone as solvent: Org. Synth. Coll., 3, 207 (1955). See also Aluminum isopropoxide, 14007. For improved conditions, see Zirconium(IV)­ tert-butoxide, 42583.

安全信息

Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes F,C
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Moisture Sensitive {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {}
UN Number UN 2925 4.1/PG 2
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S8 Keep container dry 保持容器干燥；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupII
Hazard Class4.1/8

其他信息

  • MOL 文件:556-91-2.mol
  • 图谱信息:叔丁醇铝(556-91-2)核磁图( 13 CNMR) 叔丁醇铝(556-91-2)红外图谱(IR1)
  • Alfa Aesar:叔丁氧基铝,tech.90% Aluminum tert-butoxide, tech. 90%(556-91-2)
  • F:8-21
  • TCI Shanghai:叔丁氧基铝 Aluminum tert-Butoxide(556-91-2)
  • Sigma Aldrich:556-91-2(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • 叔丁醇铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0804 叔丁氧基铝 Aluminum tert-Butoxide 5G 511元 2011/04/16 A0804 叔丁氧基铝 Aluminum tert-Butoxide 25G 951元 2010/05/25 89891 Aluminum tert-butoxide, 97% 25g 1273元
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Aluminum - Lewis Acids
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Aluminum - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum

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