Di-tert-butylchlorophosphine 二叔丁基氯化膦
CAS 13716-10-4 MFCD00008815
化学结构图
SMILES: CC(C)(C)P(Cl)C(C)(C)C
化学属性
| Mol. Formula | C8H18ClP |
|---|---|
| Mol. Weight | 180.66 |
| Density | 0.951 g/mL at 25 °C(lit.) |
| Refractive index | 1.4810 to 1.4850 |
| Flash Point | 62°C(lit.) |
| TSCA | No |
| Boiling Point | 72°C/13mmHg(lit.) |
| Appearance | colorless to light yellow liq. |
| Stability | air sensitive, moisture sensitive |
| Melting Point | 2-3°C |
别名和识别编码
| Chemical Name | Di-tert-butylchlorophosphine |
|---|---|
| Synonym | Phosphonous dichloride, bis[1,1-dimethylethyl]- di(t-butyl)chlorophosphine Phosphinous chloride, P,P-bis(1,1-dimethylethyl)- di-tert-butylchlorophosphine Phosphinous chloride, bis(1,1-dimethylethyl)- Bis(1,1-dimethylethyl)-phosphinous chloride Di-t-butylchlorophosphine Di-tert-butylchlorphosphan Chlorodi-tert-butylphosphine 二叔丁基氯化膦 Chlordi-tert.-butylphosphin Di-tert-butyl chlorophosphine Di-tert-butylphosphinous chloride |
| MDL Number | MFCD00008815 |
| CAS Number | 13716-10-4 |
| PubChem Substance ID | 87560114 |
| Reaxys-RN | 1847423 |
| Chemical Name Translation | 二叔丁基氯化膦 |
| LabNetwork Molecule ID | LN00200557 |
| InChIKey | MCRSZLVSRGTMIH-UHFFFAOYSA-N |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
相关文献及参考
- Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
- Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different b
安全信息
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S25 Avoid contact with eyes 避免眼睛接触；
GHS Symbol
- H227 Combustible liquid 可燃液体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P403+P235
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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