Triethylsilane 三乙基硅烷
CAS 617-86-7 MFCD00009018
化学结构图
SMILES: CC[SiH](CC)CC
化学属性
| Mol. Formula | C6H16Si |
|---|---|
| Mol. Weight | 116 |
| Density | 0.728 |
| Refractive index | 1.4110 to 1.4130 |
| Boiling Point | 107-108 |
| Flash Point | -3°C(lit.) |
| TSCA | Yes |
| Melting Point | -157° |
| Stability | 对湿度敏感 |
| Appearance | 无色透明液体 |
| Danger-Level | 甲类 |
别名和识别编码
| Chemical Name | Triethylsilane |
|---|---|
| Synonym | (C2H5)3SiH CT2523 NSC 93579 Triethylhydrosilane Triethylsilicon hydride NSC 93579, Triethylhydrosilane, Triethylsilicon hydride Silane, triethyl- Triethyl-silane Triethylhydrosilane Triethylsilane,98+% Triethylsilane,99% Triethylsilicon Triethylsilicon hydride Triethylsilyl Triethylsilyl hydride Triäthylsilan triethyl-silan triethylsilane |
| CAS Number | 617-86-7 |
| EC Number | 210-535-3 |
| Beilstein Registry Number | 1098278 |
| MDL Number | MFCD00009018 |
| PubChem Substance ID | 87576536 |
| Reaxys-RN | 1098278 |
| Chemical Name Translation | 三乙基硅烷 |
| LabNetwork Molecule ID | LN00241404 |
| InChI | InChI=1S/C6H15Si/c1-4-7(5-2)6-3/h4-6H2,1-3H3 |
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分类
- {SNA} Chemical Synthesis, Reduction, Silanes, Synthetic Reagents
- {uni_hamburg} no charge; 1fragment
产品应用
- 用于 2-色原烷醇还原反应的研究；与 TES 可观察到顺式选择性。
相关文献及参考
- Short: II/25D
- High-yield, selective hydrodehalogenation of alkyl and aryl halides is catalyzed by PdCl2, avoiding the skeletal rearrangements of alkyl halides sometimes observed with Lewis acid catal
- For use as a superior cation scavenger in peptide synthesis, see Triisopropylsilane, L09585.
- In combination with TFA, "ionic hydrogenation" of alkenes occurs. This can be a useful alternative to catalytic hydrogenation, since selective reduction, e.g. of the more branched double bond of a diene can be achieved. For a review of ionic hydrogenation, see: Synthesis, 633 (1974):
- Short: III/35C4
- In combination with indium(III) chloride and a radical initiator, generates a radical reagent, analogous to Tri-n-butyltin hydride, A13298, which effects dehalogenation of alkyl halides to alkanes and radical addition of halides to alkenes, including dehalocyclizations: Org. Lett., 6, 4981 (2004).
- For
- Aryl halides have been silylated using PtO2 as a catalyst, to give aryltriethylsilanes: Org. Let.., 8, 931 (2006).
- ɑß-Enones are reduced selectively to saturated ketones In the presence of TFA: Synthesis, 420 (1973); or Wilkinson's catalyst (Chlorotris(triphenylphosphine)
- In the presence of Ti(O-i-Pr)4, phosphine oxides can be reduced to phosphines, a useful alternative to pyrophoric HSiCl3: Tetrahedron Lett., 35, 625 (1994).
- Merck: 14,10372 Beilstein:4,625
- ɑß-Enones are reduced selectively to saturated ketones In the presence of TFA: Synthesis, 420 (1973); or Wilkinson's catalyst (Chlorotris(triphenylphosphine)rhodium(I), 10468): Tetrahedron Lett., 5035 (1972); Organometallics, 1, 1390 (1982).
- High-yield, selective hydrodehalogenation of alkyl and aryl halides is catalyzed by PdCl2, avoiding the skeletal rearrangements of alkyl halides sometimes observed with Lewis acid catalysts such as AlCl3: Organometallics. 15, 1508 (199
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R52/53
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
其他信息
- MSDS 信息:Triethylsilane(617-86-7).msds
- 三乙基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010058 三乙基硅烷 100ml 220元 2011/08/23 xw010204 三乙基硅烷 250ml 530元 2011/04/16 T0662 三乙基硅烷 Triethylsilane 250ML 1980元
- Acros Organics:三乙基硅烷 Triethylsilane, 99%(617-86-7)
- 海关编码:29310095
- MOL 文件:617-86-7.mol
- 用途一:用于有机合成及医药中间体
- 下游产品:4-苄基哌啶 --> 6,7-二甲氧基-3-甲基-1,2,3,4-四氢异喹啉盐酸盐
- 图谱信息:三乙基硅烷(617-86-7)红外图谱(IR1) 三乙基硅烷(617-86-7)质谱(MS) 三乙基硅烷(617-86-7)核磁图( 13 CNMR) 三乙基硅烷(617-86-7)核磁图( 1 HNMR)
- 用途二:用于有机合成及医药中间体。
- 水中分解。
- Alfa Aesar:三乙基硅烷,98+% Triethylsilane, 98+%(617-86-7)
- F:10-21
- TCI Shanghai:三乙基硅烷 Triethylsilane,>;98.0%(GC)(617-86-7)
- Sigma Aldrich:617-86-7(sigmaaldrich)
- 敏感性:Moisture Sensitive
- TSCA:Yes
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