Acrolein Diethyl Acetal 丙烯醛缩二乙醇

CAS 3054-95-3 MFCD00009239

化学结构图

3054-95-3
SMILES: C=CC(OCC)OCC

化学属性

Mol. FormulaC7H14O2
Mol. Weight130.18
Density0.854
Refractive index1.4000 to 1.4030
Flash Point15°C(lit.)
TSCANo
Boiling Point124°C
Solubility不溶于水。

别名和识别编码

Chemical NameAcrolein Diethyl Acetal
Synonym 1,1-DIETHOXY-2-PROPENE 1,1-Diethoxy-2-propene 2-Propenaldiethylacetal 2-propenal diethyl acetal 3 3-DIETHOXYPROPENE 3 3-DIETHOXYPROPENE 99% 3,3-diethoxy-1-propen 3,3-diethoxy-propene 3,3-diethoxyprop-1-ene 3,3-diethoxypropene 3,3-二乙氧基丙烯 3，3-二乙氧基丙烯 ACROLEIN ACETAL ACROLEIN DIETHYL ACETAL Acrolein Diethyl Acetal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00009239
CAS Number3054-95-3
EC Number221-276-0
Beilstein Registry Number1,727
PubChem Substance ID87562208
Chemical Name Translation丙烯醛缩二乙醇
Reaxys-RN1701567
Wiswesser Line Notation2OYO2&1U1
LabNetwork Molecule IDLN00196392
InChIInChI=1S/C7H14O2/c1-4-7(8-5-2)9-6-3/h4,7H,1,5-6H2,2-3H3
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Beilstein:1,727
  • Short: III/38B
  • Short: EINECS
  • Heck coupling (see Palladium(II)­ acetate, 10516) occurs with aryl or vinyl bromides in the presence of morpholine or piperidine: J. Org. Chem., 46, 1061 (1981); J. Chem. Soc., Perkin 1, 2597 (1987):
  • In the presence of acid, generates the ethoxyallyl cation which is a powerful dienophile, undergoing Diels-Alder reactions at low temperatures: J. Am. Chem. Soc., 109, 2182 (1987).
  • Protected acrolein equivalent. Reacts with Grignard reagents (CuBr catalysis) to give predominantly (Z)-enol ethers which can be hydrolyzed to 3-substituted propionaldehydes: Tetrahedron Lett., 3833 (1975). The (E)-enol ether is formed selectively with a Ni(II)-phosphine catalyst: Chem. Lett., 351 (1985).

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R11 Highly flammable 非常易燃
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P352+P332+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P241+P242+P243
  • P403+P235
RTECSAS1370000
Packing GroupII
UN Number 2374
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F;Xi
Hazard Class3
Storage condition +4°C 2-8°C 4 4℃
Warnings 危化品目录(2015) 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   1,259,1980

Restrict 危险品

其他信息

  • 可燃性危险特性:易燃
  • Alfa Aesar:丙烯醛缩二乙醇,94% Acrolein diethyl acetal, 96%(3054-95-3)
  • TCI Shanghai:丙烯醛缩二乙醇 Acrolein Diethyl Acetal,>;95.0%(GC)(3054-95-3)
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运存放
  • 灭火剂:干粉, 二氧化碳; 1211; 泡沫
  • F:8-13
  • 类别:易燃液体
  • 丙烯醛缩二乙醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0640 丙烯醛二乙缩醛 Acrolein Diethyl Acetal 25G 495元 2014/06/02 A0640 丙烯醛二乙缩醛 Acrolein Diethyl Acetal 250G 2570元 2010/06/21 102770250 丙烯醛缩二乙醇 Acrolein diethyl acetal 94% 25 GR 663元
  • MSDS 信息:3,3-二乙氧基丙烯(3054-95-3).msds
  • Acros Organics:3,3-二乙氧基丙烯 Acrolein diethyl acetal, 90%(3054-95-3)
  • 外观性质:无色液体。
  • 图谱信息:丙烯醛缩二乙醇(3054-95-3)核磁图( 13 CNMR) 丙烯醛缩二乙醇(3054-95-3)质谱(MS) 丙烯醛缩二乙醇(3054-95-3)红外图谱(IR2) 丙烯醛缩二乙醇(3054-95-3)红外图谱(IR1) 丙烯醛缩二乙醇(3054-95-3)核磁图( 1 HNMR)
  • 爆炸物危险特性:与空气混合形成爆炸性混合物
  • Sigma Aldrich:3054-95-3(sigmaaldrich)
  • MOL 文件:3054-95-3.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds

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