Propyl acetate 乙酸丙酯

CAS 109-60-4 MFCD00009372

化学结构图

109-60-4
SMILES: CCCOC(C)=O

化学属性

Mol. FormulaC5H10O2
Mol. Weight102
Density0.888
Refractive index1.3830 to 1.3860
Autoignition Point842 °F
Vapor Density3.5 (vs air)
Boiling Point101°C
Vapor Pressure25 mmHg ( 20 °C)
Melting Point-95
Flash Point13°C(lit.)
TSCAYes
Solubility微溶于水,溶于醇、酮、酯、油类等多数有机溶剂。

别名和识别编码

Chemical NamePropyl acetate
CAS Number109-60-4
EC Number203-686-1
Beilstein Registry Number2(4)138
MDL NumberMFCD00009372
Synonym Propylacetat Acetate de propyle normal Essigsäurepropylester 1-Propyl acetate Acetic acid, propyl ester 醋酸正丙酯;乙酸丙酯;醋酸丙酯 乙酸正丙酯 C5H10O2 (acetic acid propyl ester) Acetic acid n-propyl ester Propyl ethanoate 乙酸丙酯 Propyl acetate 1-propyl acetate n-Propylacetat n-Propanol acetate Ethanoic acid, propyl ester Essigsäure-n-propylester Propylester kyseliny octove n-Propyl acetate; Acetic acid propyl ester acetic acid propyl ester 1-Acetoxypropane Acetic Acid Pro n-Propyl ethanoate 醋酸正丙酯,乙酸丙酯 Ethanoic acid propyl ester Normal propyl acetate n-Propyl acetate
PubChem Substance ID7997
Merck Number7841
Reaxys-RN1740764
Chemical Name Translation乙酸丙酯
Wiswesser Line Notation3OV1
LabNetwork Molecule IDLN00194938
InChIInChI=1S/C5H10O2/c1-3-4-7-5(2)6/h3-4H2,1-2H3
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分类

  • {SNA} Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O - Z, O-P, O-Z
  • {SNA} Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O-P, O-Z
  • {SNA} Alphabetical Listings, Certified Food Grade Products, Certified Natural Products, Flavors and Fragrances, Follows IFRA Guidelines, Food Safe Elite, Halal Certified Products, Kosher Certified Products, N-P, O - Z, O-P, O-Z
  • {SNA} Alphabetical Listings, Certified Foo

产品应用

  • 醋酸正丙酯对多种合成树脂有优良的溶解能力,是乙基纤维素、硝酸纤维素、苯乙烯、甲基丙烯酸酯树脂等许多合成树脂的有效溶剂。醋酸正丙酯常用于有机合成,是用作涂料、印刷油墨等的溶剂,醋酸正丙酯也是工业常用的脱水剂。

相关文献及参考

  • Short: II/27B
  • Short: II/5
  • Short: III/38A
  • Merck:14,7841
  • Merck:14,7841 Beilstein:2(4)138

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S29 Do not empty into drains 不要排入下水道;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S2 Keep out of the reach of children 避免儿童触及;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36 Irritating to eyes 刺激眼睛
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P307+P311
  • P337+P313
  • P304+P340
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340+P312
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
Hazard statements
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAJ3675000
Packing GroupII
UN Number 1276
Hazard Codes F;Xi 3
Storage condition 密封阴凉保存。
Hazard Class3
Warnings 危化品目录(2015)
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 38 gm/m3/5H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Gastrointestinal - changes in structure or function of salivary glands
   Blood - other changes
REFERENCE :
   AGGHAR Archiv fuer Gewerbepathologie und Gewerbehygiene.  (Berlin, Ger.)
   V.1-18, 1930-61.  For publisher information, see IAEHDW.
   Volume(issue)/page/year: 5,1,1933

TYPE OF TEST            : LD50 - Lethal dose, 5

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 9370 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Skin and Appendages - hair
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 2,327,1964

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 1/25/1965

{hazard

Restrict 危险品

其他信息

  • 有梨样香气。能与乙醇、乙醚混溶,微溶于水(16℃时,1.6:100)。易燃,高浓度时有麻醉性,有刺激性。

系列性分类