Tetrabutyltin 四正丁基锡

CAS 1461-25-2 MFCD00009422

化学结构图

1461-25-2
SMILES: CCCC[Sn](CCCC)(CCCC)CCCC

化学属性

Mol. FormulaSn(C4H9)4
Mol. Weight347
Density1.057 g/mL at 25 °C(lit.)
Refractive index1.4720 to 1.4740
Flash Point107°C(lit.)
TSCAYes
Melting Point-97 °C(lit.)
Boiling Point302°C(lit.)
Solubility不溶

别名和识别编码

Chemical NameTetrabutyltin
Synonym (C4H9)4Sn C16H36Sn (tetrabutyl-stannane) Stannane, tetrabutyl- TETRA-N-BUTYLSTANNANE TETRA-N-BUTYLTIN TETRA-NORMAL-BUTYLTIN TETRABUTYLSTANNANE TETRABUTYLTIN TETRABUTYLTIN(IV) TIN TETRABUTYL Tetra-n-butylcin Tetra-n-butylstannane Tetra-n-butylstannane~Tin tetrabutyl Tetra-n-butyltin Tetra-n-butyltin, 94% min Tetra-n-butyltin, min. 94% Tetra-n-butyltin, tech., 93% Tetra-n-butyltin,min.94% Tetra-n-butylzinn Tetrabutyl stannane Tetrabutylstannane Tetrabutyltin Tetrabutyltintech Tetrabutylzinn Tin tetra-n-butyl Tin tetrabutyl Tin, tetrabutyl- Zinntetrab
MDL NumberMFCD00009422
CAS Number1461-25-2
EC Number215-960-8
PubChem Substance ID15098
Beilstein Registry Number3648237
Reaxys-RN3648237
Chemical Name Translation四正丁基锡
Wiswesser Line Notation4-SN-4&4&4
InChIInChI=1S/4C4H9.Sn/c4*1-3-4-2;/h4*1,3-4H2,2H3;
LabNetwork Molecule IDLN00194946
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins

相关文献及参考

  • Short: III/35C4
  • Short: III/35D5
  • Beilstein: 4,IV,4312

安全信息

RTECSWH8605000
Packing GroupIII
UN Number 1760 2788 UN2788 UN 1760 8/PG 2
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R48/23/25
  • R50/53
  • R48/23
Safety Statements
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P312
  • P301+P312+P330
  • P301+P316
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P317
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes T,N T;N
Hazard Class6.1
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02221

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 174 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - muscle weakness
REFERENCE :
   APFRAD Annales Pharmaceutiques Francaises.  (SPPIF, B.P.22, F-41353 Vineuil,
   France)  V.1-    1943-  Volume(issue)/page/year: 14,88,1956

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 15,3,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page

TYPE OF TE

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3916 mg/kg
SEX/DURATION            : female 13-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 16,71,1996

Restrict 危险品

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 四丁基锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0058 四丁基锡 Tetrabutyltin 25G 222元 2014/06/02 T0058 四丁基锡 Tetrabutyltin 500G 1940元 2010/06/21 137980050 四丁基锡 Tetra-n-butyltin 96% 5 GR 216元
  • 外观性质:无色或微黄色油状液体。
  • 灭火剂:二氧化碳、砂土、水、泡沫
  • 刺激数据:眼睛-兔子 500 毫克/24小时 轻度
  • 毒性分级:低毒
  • 下游产品:二丁基氧化锡 --> 二月桂酸二丁基锡 --> 丁基三氯化锡 --> 单丁基氧化锡
  • 用途一:是制造有机物热稳定剂和有机锡催化剂(如二丁基氧化锡、二丁基二月桂酸锡等)的重要中间体,用作汽油防爆剂
  • TSCA:Yes
  • Acros Organics:四正丁基锡 Tetra-n-butyltin, 96%(1461-25-2)
  • MOL 文件:1461-25-2.mol
  • 急性毒性:口服-小鼠 LD50: 6000 毫克/公斤
  • Alfa Aesar:四正丁基锡,94%min Tetra-n-butyltin, 95%(1461-25-2)
  • Sigma Aldrich:1461-25-2(sigmaaldrich)
  • 职业标准:TWA 0.1 毫克 (锡)/立方米; STEL 0.2 毫克 (锡)/立方米
  • 海关编码:29310095
  • MSDS 信息:四丁基锡(1461-25-2).msds
  • TCI Shanghai:四丁基锡 Tetrabutyltin,>;95.0%(GC)(1461-25-2)
  • 图谱信息:四丁基锡(1461-25-2)核磁图( 13 CNMR) 四丁基锡(1461-25-2)核磁图( 1 HNMR) 四丁基锡(1461-25-2)红外图谱(IR1) 四丁基锡(1461-25-2)质谱(MS)
  • 类别:有毒物品

系列性分类


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