Benzyl Butyl Phthalate 邻苯二甲酸丁苄酯

CAS 85-68-7 MFCD00009440

化学结构图

85-68-7
SMILES: CCCCOC(=O)C1C=CC=CC=1C(=O)OCC1C=CC=CC=1

化学属性

Mol. Formula2-[CH3(CH2)3O2C]C6H4CO2CH2C6H5
Mol. Weight312
Refractive index1.5380 to 1.5420
Density1.1 g/mL at 25 °C(lit.)
Flash Point213°C(lit.)
TSCAYes
Boiling Point250°C/22.5mmHg(lit.)
Autoignition Point450 °F
Vapor Density10.8 (vs air)
Vapor Pressure0.16 mmHg ( 150 °C)
Melting Point<-35 ºC
Solubility0.000269 G/100 ML

别名和识别编码

Chemical NameBenzyl Butyl Phthalate
CAS Number85-68-7
Synonym phthalicacidbenzylesterbutyles S 160 {Chem BENZYL BUTYL PHTHALA phthalic acid benzyl ester-butyl ester Benzylbutylphtalat {Chemical Santicizer S 160 {Chemica 邻苯二甲酸丁苄酯 1-B 苄基正丁基邻苯二甲酸酯 PHTHALIC ACID, BENZYLBUTYL ES Phthalsäure, Benzylbutylester 1,2-Benzenedicarboxylic acid butyl phenylmethyl ester; Butyl phenylmethyl 1,2-benzenedicarboxylate; Benzyl butyl phthalate; Butyl benzyl phthlate; BBP Palatinol BB Diacizer D 160 BBP 1,2-Benzoldicarbonsäurebutylphenylmethylester 增塑剂BBP BUTYL BENZYL PHTHALATE NCI-C54375 Sicol 160 Ketjenflex 160 {uni_hambu B Benzylbutylphthalat PHTHALIC ACID BENZYL N-BUTYL ES
PubChem Substance ID87574523
EC Number201-622-7
Beilstein Registry Number2062204
MDL NumberMFCD00009440
Reaxys-RN2062204
Chemical Name Translation邻苯二甲酸丁苄酯
Wiswesser Line NotationQVR BVO1R
LabNetwork Molecule IDLN00226134
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分类

  • {SNA} B, Bioactive Small Molecules, Materials Science, Plasticizers, Polymer Additives, Polymer Science, 细胞生物学
  • {SNA} 2000/60/EC, A-B, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,

产品应用

  • 主要用作增塑剂。

相关文献及参考

  • Engel, S., et al.: Neurotoxicology, 30, 522 (2009),
  • Reyes, F., et al.: J. Clin. Endocrinol. Metab., 37, 74 (1973),
  • Short: EINECS
  • Short: IV/20B
  • Short: IV/18B
  • Beilstein: 9,II,594

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T,N
RTECSTH9990000
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P308+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P304+P340
  • P405 Store locked up. 上锁保管。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P304+P340+P312
  • P305+P351+P338+P337+P313
  • P305+P351+P338
Signal word
UN Number UN3082 3082
Risk Statements
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R50/53
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupIII
Hazard Class9
Storage condition 冷藏(4℃)和避光下保存 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 364 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-458,1997

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 433 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - leukemia
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-213,1982

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 437 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - leukemia
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 65,271,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4170 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 29,193,1982

{hazar

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(6),25,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13700 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 32(7),52,1988

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 2 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 356,85,1996

TYPE OF

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 4900 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 12,57,1992

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 21 gm/kg
SEX/DURATION            : male 14 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 4,136,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 23300 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB91-129999

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE

其他信息

  • 灭火剂:泡沫、二氧化碳、干粉
  • 蒸气密度:10.8 (vs air)
  • 蒸气压:0.16 mm Hg ( 150 °C)
  • Alfa Aesar:苄基正丁基邻苯二甲酸酯,98% Benzyl n-butyl phthalate, 98%(85-68-7)
  • 海关编码:29173400
  • 图谱信息:邻苯二甲酸丁苄酯(85-68-7)红外图谱(IR1) 邻苯二甲酸丁苄酯(85-68-7)核磁图( 13 CNMR) 邻苯二甲酸丁苄酯(85-68-7)质谱(MS) 邻苯二甲酸丁苄酯(85-68-7)红外图谱(IR2) 邻苯二甲酸丁苄酯(85-68-7)核磁图( 1 HNMR) 邻苯二甲酸丁苄酯(85-68-7)Raman光谱
  • 毒性分级:中毒
  • MSDS 信息:酞酸苄基丁酯(85-68-7).msds
  • MOL 文件:85-68-7.mol
  • 方法一:由苯酐和丁醇经酯化得邻苯二甲酸单丁酯[131-70-4]，然后在碳酸钠存在下与氯化苄进行第二次酯化，经液碱中和、水洗后进行减压蒸馏而得。原料消耗(kg/t)苯酐（98%） 560丁醇 290氯化苄 620碳酸钠 320
  • 用途二:主要用作增塑剂。具有很强的溶解能力，与聚氯乙烯树脂、乙酸乙烯树脂、聚苯乙烯、硝酸纤维素的互溶性较好，具有良好的耐污染性，塑化速度快，填充剂容量大，耐水和耐油抽出。可作主增塑剂使用。常与其他增塑剂配合，用于含大量填充剂的塑料地板、装饰材料、瓦楞板等。该品用于制造薄膜、板材和管材，可获得具有优良透明性和光滑表面的制品，还用于压延法制泡沫人造革。
  • 凝固点:-35℃
  • 用途三:用作聚氯乙烯、氯乙烯共聚物、纤维素树脂、天然橡胶和合成橡胶的增塑剂。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
  • 用途一:用作聚氯乙烯、氯乙烯共聚物、纤维素树脂、天然和合成橡胶的增塑剂
  • Sigma Aldrich:85-68-7(sigmaaldrich)
  • 类别:易燃液体
  • 可燃性危险特性:遇明火、高温、强氧化剂、酸较易燃；燃烧排放刺激烟雾
  • 上游原料:苄基氯 --> 邻苯二甲酸单丁酯
  • 用途四:主要用作增塑剂。具有很强的溶解能力，与聚氯乙烯树脂、乙酸乙烯树脂、聚苯乙烯、硝酸纤维的互溶性交好，具有良好的耐污染性，塑化速度快，填充剂容量大，耐水和耐油抽出。可作主增塑剂使用，常与其他增塑剂配合，用于含大量充剂的塑料地板，装饰材料、瓦楞板等。改频用于制造薄膜、板材和管材，可获得具有优良透明性和光滑表面的制品，还用于压延法制泡沫人造革。
  • 外观性质:透明油状液体，微具芳香味。
  • 急性毒性:口服- 大鼠 LD50: 2330 毫克/ 公斤; 口服- 小鼠 LD50: 4170 毫克/ 公斤
  • 储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂、酸分开存放
  • TCI Shanghai:邻苯二甲酸苄基丁基酯 Benzyl Butyl Phthalate,>;98.0%(GC)(85-68-7)
  • 爆炸物危险特性:可与氧化剂激烈反应
  • 邻苯二甲酸丁苄酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0288 邻苯二甲酸苄基丁基酯 Benzyl Butyl Phthalate 500G 527元 2014/06/02 P0288 邻苯二甲酸苄基丁基酯 Benzyl Butyl Phthalate 25G 237元 2010/05/25 B24769 苄基 正丁基 邻苯二甲酸酯, 98% Benzyl n-butyl phthalate, 98% 2.5kg 5474元
  • 职业标准:TWA 3 毫克/公斤; STEL 5 毫克/公斤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. European Community: ISO, DIN and DL 152 - Method Specific
  5. 2000/60/EC - European Community: ISO, DIN and DL 152
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BA - BH - B
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Cosmetic Standards - Chromatography
  5. Allergens - Cosmetic Standards
  6. Phthalates - Allergens
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymer Additives - Polymer Science
  4. Plasticizers - Polymer Additives
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Certified Reference Materials (CRMs) - Analytical Standards
  4. Organic CRMs TraceCERT - Certified Reference Materials (CRMs)
  5. CRM for chromatography - Organic CRMs TraceCERT
  6. Organic CRMs Alphabetical - CRM for chromatography
  1. Analytical & Chromatography 分析化学与色谱
  2. Environmental Endocrine Disruptors
  1. Materials Science 材料科学
  2. Plasticizer