2-Hexyne 2-己炔
CAS 764-35-2 MFCD00009470
化学结构图
SMILES: CC#CCCC
化学属性
| Mol. Formula | CH3(CH2)2C |
|---|---|
| Mol. Weight | 82 |
| Refractive index | 1.4120 to 1.4150 |
| Boiling Point | 84-85 |
| Density | 0.731 |
| Flash Point | -10°C(lit.) |
| TSCA | No |
| Melting Point | -90° |
| Solubility | 不溶于水，溶于苯，可混溶于乙醇、乙醚。 |
别名和识别编码
| Chemical Name | 2-Hexyne |
|---|---|
| CAS Number | 764-35-2 |
| PubChem Substance ID | 33629 |
| EC Number | 212-117-6 |
| Beilstein Registry Number | 1731542 |
| MDL Number | MFCD00009470 |
| Reaxys-RN | 1731542 |
| Synonym | Methylpropylacetylen {uni_hamburg} C3H7CequivCCH3 2-Hexyne,98+% 2-hexyne hex-2-yne 甲基丙基乙炔 1-methyl-2-propylacetylene 2-HEXYNE 2-Hexin METHYL-N-PROPYLACETYLENE 2-已炔 Hex-2-yne methyl(propyl)acetylene 2-已炔,98+% Methyl propyl acetylene 1-Methyl-2-propylacetylene 2-己炔 |
| Chemical Name Translation | 2-己炔 |
| InChIKey | MELUCTCJOARQQG-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01742524 |
| InChI | InChI=1S/C6H10/c1-3-5-6-4-2/h3,5H2,1-2H3 |
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分类
- Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
- {SNA} Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
相关文献及参考
- Short: II/27B
- 2-Alkynes are metallated almost exclusively at the terminal position by t-BuLi + TMEDA in ether. Subsequent reaction with, e.g. TMS chloride gives propargylic silanes: Synthesis, 111 (1984).
- On heating under pressure wit
- On heating under pressure with norbornene and CO in the presence of Dodecacarbonyltriruthenium, 10507, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998):
- 2-Alkynes are metallated almost exclusively at the terminal position by t-BuLi + TMEDA in ether. Subsequent reaction with, e.g. TMS chloride gives propargylic silanes: Synthesis, 111 (1984).
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- P303+P361+P353
- P337+P313
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P403+P235
其他信息
- 图谱信息:2-已炔(764-35-2)核磁图( 1 HNMR) 2-已炔(764-35-2)核磁图( 13 CNMR) 2-已炔(764-35-2)红外图谱(IR1) 2-已炔(764-35-2)质谱(MS)
- Acros Organics:2-Hexyne, 99%(764-35-2)
- 2-已炔价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0429 2-己炔 2-Hexyne 5ML 266元 2014/06/02 H0429 2-己炔 2-Hexyne 25ML 798元 2010/05/25 B22405 2-已炔, 98+% 2-Hexyne, 98+% 50g 1890元
- Alfa Aesar:2-已炔,98+% 2-Hexyne, 98+%(764-35-2)
- MSDS 信息:2-己炔(764-35-2).msds
- MOL 文件:764-35-2.mol
- 外观性质:无色液体。
- TCI Shanghai:2-己炔 2-Hexyne,>;98.0%(GC)(764-35-2)
- Sigma Aldrich:764-35-2(sigmaaldrich)
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