Bis(Triphenylphosphine)Dicarbonylnickel 双(三苯基膦)二羰基镍

CAS 13007-90-4 MFCD00009591

化学结构图

13007-90-4
SMILES: [Ni].[C-]#[O+].[C-]#[O+].C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. Formula[(C6H5)3P]2Ni(CO)2
Mol. Weight639.28
TSCANo
Melting Point206-209 °C(lit.)

别名和识别编码

Chemical NameBis(Triphenylphosphine)Dicarbonylnickel
MDL NumberMFCD00009591
EC Number235-851-9
CAS Number13007-90-4
Merck Number14,1304
Synonym 双三苯基膦二羰基镍 Nickel(0)bis(triphenylphosphine) dicarbonyl 二羰基双(三苯基膦)镍(0) 双三苯基膦二羰基镍(0)
PubChem Substance ID24852811
Chemical Name Translation双(三苯基膦)二羰基镍
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel, Non-Precious Metal Catalysis

相关文献及参考

安全信息

Safety Statements
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S4 Keep away from living quarters 远离生活区；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Packing GroupII
UN Number UN3466
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R45 May cause cancer 可能致癌
  • R42/43
WGK Germany3
GHS Symbol
Precautionary statements
  • P308+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
Signal word Danger
Hazard statements
  • H350 May cause cancer 可能致癌
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Nickel - 镍催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Nickel - 镍催化剂
  1. Functional Group 官能团索引
  2. phosphine

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