2-Chlorophenylphosphoryl Dichloride 2-氯苯基二氯膦[磷酸化剂]

CAS 15074-54-1 MFCD00009704

化学结构图

15074-54-1
SMILES: O=P(Cl)(Cl)OC1C=CC=CC=1Cl

化学属性

Mol. FormulaC6H4Cl3O2P
Mol. Weight245.42
Density1.491 g/mL at 25 °C(lit.)
Refractive index1.5370 to 1.5400
Flash Point105°C(lit.)
TSCANo
Boiling Point256°C(lit.)

别名和识别编码

Chemical Name2-Chlorophenylphosphoryl Dichloride
Synonym dichlorophosphoric acid-(2-chloro-phenyl ester) 2-Chlorphenyl-dichlorphosphat 2-Chlorophenyl dichlorophosphate 2-Chlorophenyl phosphodichloridate 2-氯苯基偶磷二氯化酯 2-chlorophenyl phosphorodichloridate (2-Chlorphenyl)-dichlorphosphat Phosphorsäure-mono-(2-chlorphenylester)-dichlorid Phosphorodichloridic acid, 2-chlorophenyl ester o-chlorophenyl dichlorophosphate 2-氯苯基二氯磷酸酯
MDL NumberMFCD00009704
EC Number239-129-4
CAS Number15074-54-1
Beilstein Registry Number911009
PubChem Substance ID87566021
Chemical Name Translation2-氯苯基二氯膦[磷酸化剂]
Reaxys-RN911009
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides

相关文献及参考

  • Short: III/39 Title: Nuclear Quadrupole Resonance Spectroscopy Data Author: Chihara, H.; Nakamura, N. Editor: Chihara, H. Source: Landolt-Börnstein, New Series Volume: III/39 Year: 1997 Keyword: NQR; spectroscopy ISBN: 3-540-62428-7 ISBN: 978-3-540-62428-8 Internet Resource: DOI:10.1007/b61951 RefComment: VIII, 424 pages. Hardcover Abstract: Volume III/39 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volumes III/20 and III/31. The literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1996 is covered. In total there are more than 10.000 substances in the volumes, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times. Volume III/39 can be consulted without recourse to its predecessor because the complete introduction and general tables are repeated from III/20 and III/31.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Reagent for formation of the internucleotide phosphate link by the phosphotriester method: Liebigs Ann. Chem., 2392 (1981); Tetrahedron, 37, 3751 (1981).

安全信息

Packing GroupIII
UN Number 3265 UN3265
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition Moisture Sensitive 0-10°C
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes C
Hazard Class8

系列性分类


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