N,N-Disuccinimidyl Carbonate N.N-二琥珀酰亚胺基碳酸酯
CAS 74124-79-1 MFCD00009767
化学结构图
SMILES: O=C(ON1C(=O)CCC1=O)ON1C(=O)CCC1=O
化学属性
| Mol. Formula | C9H8N2O7 |
|---|---|
| Mol. Weight | 256 |
| Melting Point | 190-215 |
| Density | 1.422 |
| TSCA | No |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | N,N-Disuccinimidyl Carbonate |
|---|---|
| Synonym | N-Succinimidyl carbonate N,N′-二琥珀酰亚胺基碳酸酯 N-琥珀酰氨基碳酸酯 DSC 二(N-琥珀酰亚胺基)碳酸酯 |
| CAS Number | 74124-79-1 |
| PubChem Substance ID | 676246 |
| EC Number | 277-730-3 |
| Beilstein Registry Number | 1499137 |
| MDL Number | MFCD00009767 |
| Chemical Name Translation | N.N-二琥珀酰亚胺基碳酸酯 |
| Reaxys-RN | 1499137 |
| LabNetwork Molecule ID | LN00170056 |
| InChIKey | PFYXSUNOLOJMDX-UHFFFAOYSA-N |
| InChI | InChI=1S/C9H8N2O7/c12-5-1-2-6(13)10(5)17-9(16)18-11-7(14)3-4-8(11)15/h1-4H2 |
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分类
- {SNA} Active Esters/Additives, Analytical Reagents, Analytical/Chromatography, Chemical Biology, Chemical Synthesis, Coupling, Derivatization Reagents, Derivatization Reagents HPLC, Peptide Chemistry, Peptide Coupling, Synthetic Reagents, UV-VIS
- Active Esters/Additives, Analytical Reagents, Analytical/Chromatography, Chemical Biology, Chemical Synthesis, Coupling, Deriv
- {SNA} Active Esters/Additives, Chemical Biology, Chemical Synthesis, Coupling, Derivatization Reagents, Derivatization Reagents HPLC,
产品应用
- 用于N-基团保护的氨基酸和其它酸的N-琥珀酰亚胺酯制备的常用试剂；用于激活的碳酸盐，如合成尿素。
相关文献及参考
- 1. J. Org. Chem. 71 , 9556, (2006) 摘要
- Tetrahedron Lett. 33 , 2781, (1992)
- J. Chem. Soc., Chem. Commun. , 1308, (1992)
- Fieser 9 ,208 / Fieser 11 ,226
- Aldrich MSDS 1 , 837:C / Corp MSDS 1 (1), 1478:C / FT-IR 1 (1), 796:D / FT-IR 2 (1), 1352:B / RegBook 1 (1), 931:L / Structure Index 1 , 145:C:3
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H301 Toxic if swallowed 吞食有毒
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P332+P313
- P305+P351+P338
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P302+P352
- P305+P351+P338+P337+P313
- P301+P312+P330
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
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