Chlorotitanium Triisopropoxide 三异丙氧化氯钛

CAS 20717-86-6 MFCD00009861

化学结构图

20717-86-6
SMILES: CC(C)O[Ti](Cl)(OC(C)C)OC(C)C

化学属性

Mol. Formula[(CH3)2CHO]3TiCl
Mol. Weight260.58
Density0.775
Melting Point35-40 °C
Flash Point31°(87°F)
TSCAYes
Boiling Point63-66°/0.1mm
Appearance fused solid to pale yellow liq.
Stabilitymoisture sensitive
pH:A

别名和识别编码

Chemical NameChlorotitanium Triisopropoxide
Synonym Chlorotitanium triisopropoxide, 1.0 M solution in dichloromethane 三異丙氧氯鈦 ORTHOTITANIC ACID TRIISOPROPYL ESTER CHLORIDE TITANIUM(IV) TRIISOPROPOXY CHLORIDE 三异丙氧基氯化钛 溶液
CAS Number20717-86-6
PubChem Substance ID24855066
Beilstein Registry Number4163222
MDL NumberMFCD00009861
Chemical Name Translation三异丙氧化氯钛
LabNetwork Molecule IDLN00163098
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Titanium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Titanium, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Titanium

相关文献及参考

  • RegBook 1 (2), 3057:J / Structure Index 1 , 484:B:8
  • Reacts with the Li enolates of ketones to give Ti(IV) enolates which undergo the aldol condensation with pronounced erythro-selectivity: Tetrahedron Lett., 22, 4691 (1981). This selectivity can be extended to aldehydes by using the Li derivatives of their N,N-dimethylhydrazones: Angew. Chem. Int. Ed., 21, 864 (1982).
  • Merck 14 ,10481
  • Fieser 14 ,87
  • In combination with cyclopentylmagnesium bromide, forms a Ti(II) species which mediates the reaction of vinyltributyltin with esters or amides to give trisubstituted cyclopropylstannanes with high diastereoselectivity: J. Org. Chem., 63, 9135 (1998).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Precautionary statements
Signal word
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
UN Number UN2921 UN 2924 3/PG 2
Risk Statements
  • R10 Flammable 易燃
  • R48/20
  • R34 Causes burns 会导致灼伤
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R51/53
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
Storage condition Moisture Sensitive Flammables area
Packing GroupII
Hazard Class4.1

其他信息

  • Alfa Aesar:三异丙氧化氯钛,95% Chlorotitanium triisopropoxide, 95%(20717-86-6)
  • 三异丙氧基氯化钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 224768000 三异丙氧基氯化钛 Chlorotitanium triisopropoxide , 1M solution in dichloromethane, AcroSeal® 800 ML 4093元 2010/06/21 224592500 三异丙氧基氯化钛 Chlorotitanium triisopropoxide 98% 250 GR 2451元 2010/06/21 224590010 三异丙氧基氯化钛 Chlorotitanium triisopropoxide 98% 1 KG 6929元
  • TSCA:No
  • Sigma Aldrich:20717-86-6(sigmaaldrich)
  • Acros Organics:三异丙氧基氯化钛 Chlorotitanium triisopropoxide, 98%(20717-86-6)
  • MOL 文件:20717-86-6.mol
  • F:3-10-21
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organocopper - Organometallic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organocopper - Organometallic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Titanium - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Tin
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Other Organometallic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Other Organometallic Reagents
  1. Alkoxide
  2. Titanium

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