(1S,2S)-(-)-1-Phenylpropylene oxide (1S,2S)-(-)-1-苯基亚丙基环氧

CAS 4518-66-5 MFCD00010400

化学结构图

4518-66-5
SMILES: C[C@@H]1O[C@H]1c1ccccc1

化学属性

Mol. FormulaC9H10O
Mol. Weight134.18
Refractive indexn20/D 1.517(lit.)
Density1.003 g/mL at 25 °C(lit.)

别名和识别编码

Chemical Name(1S,2S)-(-)-1-Phenylpropylene oxide 98%
Synonym Oxirane, 2-methyl-3-phenyl-, (2S-trans)- Benzene, (1,2-epoxypropyl)-, (S,S)- (-)-trans-2-Methyl-3-phenyloxirane (2S,3S)-(-)-2-甲基-3-苯基环氧乙烷 Oxirane, 2-methyl-3-phenyl-, (2S,3S)- (1S,2S)-1,2-epoxy-1-phenyl-propane (S,S)-Phenylpropylene oxide {uni_hamburg} (2S,3S)-(-)-2-甲基-3-苯基环氧乙烷 反式-(-)-2-甲基-3-苯基环氧乙烷 (1S,2S)-(-)-trans-1-Phenylpropene oxide 反式-(-)-2-甲基-3-苯基环氧乙烷 (2S,3S)-(-)-3-methyl-2-phenyloxirane (1S,2S)-(-)-1-Phenylpropylene oxide (1S,2S)-trans-1-Phenyl-1,2-epoxypropane (2S,3S)-2-Methyl-3-phenyl-oxirane (1S,2S)-(-)-1-苯基亚丙基环氧
CAS Number4518-66-5
PubChem Substance ID24857293
MDL NumberMFCD00010400
Chemical Name Translation(1S,2S)-(-)-1-苯基亚丙基环氧
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; aromatic; alicycle; 3ring; 6ring; ether; chiral; 1fragment
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks

相关文献及参考

  • Beil. 17 ,IV,412
  • Corp MSDS 1 (2), 2795:B / FT-NMR 1 (2), 221:B / RegBook 1 (1), 1251:F / Structure Index 1 , 191:C:5
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks

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