1,2-Bis(Trimethylsilyloxy)Cyclobutene 1,2-双(三甲基硅氧基)环丁烯

CAS 17082-61-0 MFCD00010798

化学结构图

17082-61-0
SMILES: C[Si](C)(C)OC1CCC=1O[Si](C)(C)C

化学属性

Mol. FormulaC10H22O2Si2
Mol. Weight230.45
Refractive index1.4320 to 1.4370
Boiling Point58-59 °C at 2 mmHg
Density0.897 g/mL at 25 °C(lit.)
Flash Point61°C(lit.)

别名和识别编码

Chemical Name1,2-Bis(Trimethylsilyloxy)Cyclobutene
CAS Number17082-61-0
PubChem Substance ID87564663
Beilstein Registry Number1367530
MDL NumberMFCD00010798
Reaxys-RN1367530
Synonym 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Bis((trimethylsilyl)oxy)cyclob
Chemical Name Translation1,2-双(三甲基硅氧基)环丁烯
Canonical SMILESC[Si](C)(C)OC1=C(CC1)O[Si](C)(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • J. Am. Chem. Soc. 106 , 1759, (1984)
  • Org. Synth. 7 , 112, (1990)
  • Corp MSDS 1 (1), 459:D / FT-IR 2 (3), 4381:D / FT-NMR 1 (3), 671:B / RegBook 1 (2), 2975:C / Structure Index 1 , 471:D:1 / Vapor Phase 3 , 1649:A

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P370+P378
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+
Signal word Warning {} {} {} {} {TCI}
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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