Germanium(IV) Chloride 氯化锗

CAS 10038-98-9 MFCD00011029

化学结构图

10038-98-9
SMILES: Cl[Ge](Cl)(Cl)Cl

化学属性

Mol. FormulaCl4Ge
Mol. Weight214.39
Boiling Point83.1°
Density1.874
Melting Point-49.5°
TSCAYes
Vapor Pressure76 mmHg ( 20 °C)
Refractive indexn20/D 1.463
Solubility分解

别名和识别编码

Chemical NameGermanium(IV) Chloride
Synonym germanium tetrachloride Germanium(IV) chloride Tetrachlorogermane Germaniumtetrachlorid 四氯化锗 Germanium( IV) chloride; Germanium tetrachloride Germanium-IV-chlorid Germanium(IV)-chlorid tetrachloro-germane Germane, tetrachloro- Germanium chloride (GeCl4) germanium (IV) chloride Germanium, tetrachloro- Germanium tetrachloride
CAS Number10038-98-9
PubChem Substance ID24855486
EC Number233-116-7
MDL NumberMFCD00011029
Merck Number14,4410
Chemical Name Translation氯化锗
Wiswesser Line Notation.GE..G4
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分类

  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium, Germanium Salts, Materials Science, Metal and Ceramic Science, Salts
  • {uni_hamburg} no charge; 1fragment
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium, Germanium Salts, Materials Science, Metal and Ceramic Science, Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ge, Germanium, Germanium Salts, Materials Science, Metal and Ceramic Science, Salts, Ultra-High Purity Materials

相关文献及参考

  • 1. Beattie, I.R. et al. Inorg. Chem. 37 , 6032, (1998) 摘要
  • Merck 14 ,4410
  • Aldrich MSDS 1 , 989:C / Corp MSDS 1 (1), 1768:D / RegBook 1 (3), 3325:B / Sax 6 , 1474
  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: II/5 Title: Molecular Acoustics Author: Schaaffs, W. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/5 Year: 1967 ISBN: 3-540-03897-3 ISBN: 978-3-540-03897-9 Internet Resource: DOI:10.1007/b19950 RefComment: 321 figs., XII, 286 pages, Hardcover
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Har

安全信息

GHS Symbol
WGK Germany3
Hazard Codes C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLY5225000
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S8 Keep container dry 保持容器干燥;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
UN Number 3390 UN3264
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
Storage condition Moisture Sensitive
Packing GroupII
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02625

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 44 gm/m3/2H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 12(5),51,1968

系列性分类