Ruthenium(III) Chloride 三氯化钌,无水

CAS 10049-08-8 MFCD00011208

化学结构图

10049-08-8
SMILES: Cl[Ru](Cl)Cl

化学属性

Mol. FormulaCl3Ru
Mol. Weight207.43
Density3.11 g/mL at 25 °C(lit.)
SolubilityInsoluble in cold water. Decomposes in hot water
TSCAYes
Melting Point500°C

别名和识别编码

Chemical NameRuthenium(III) Chloride
MDL NumberMFCD00011208
PubChem Substance ID87575631
CAS Number10049-08-8
EC Number233-167-5
Merck Number8302
Synonym Ruthenium(III) chloride {LY} Ruthenium(III) chloride {} {LY} Ruthenium(III) chloride {} {} {LY} Ruthenium(III) chloride {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ruthenium(III) chloride {} {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number2384789
Chemical Name Translation三氯化钌,无水
Wiswesser Line Notation.RU..G3
LabNetwork Molecule IDLN00194344
Canonical SMILESCl[Ru](Cl)Cl
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分类

  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Ru Catalysts, Ruthenium, Ruthenium Salts, Salts
  • {SNA} ATRP, ATRP Metal Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Research Essentials, Ru Catalysts, Ruthenium Catalysts, Ruthenium Salts, Salts, 材料科学
  • {SNA} ATRP, ATRP Metal Salts, Catalysis and
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于 1,7-二烯氧化环化生成氧杂环庚二醇的催化剂。用高碘酸盐或溴酸盐使环醚的叔碳氢键羟基化。

相关文献及参考

  • 1. Tetrahedron Lett. 48 , 5131, (2007)
  • 2. J. Org. Chem. 72 , 5820, (2007) 摘要
  • Kobayashi, S.; Kakumoto, K.; Sugiura, M. Org. Lett. 4 , 1319, (2002) 摘要
  • Ma, S.; Zhang, J. J. Am. Chem. Soc. 125 , 12386, (2003) 摘要
  • Huang, R.; Shaughnessy, K. H. Chem. Commun. , 4484, (2005) 摘要
  • Merck 14 ,8302
  • Fieser 11 ,462 / Fieser 13 ,268 / Fieser 15 ,280
  • Corp MSDS 1 (2), 3060:A / RegBook 1 (3), 3339:A / Sax 6 , 2376
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSVM2650000
WGK Germany3
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes 8 C
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
UN Number 3260
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 360 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

其他信息

  • 不溶于水

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Ru Catalysts - Ruthenium
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Ruthenium Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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