Antimony(V) Fluoride 氟化锑(V)

CAS 7783-70-2 MFCD00011219

化学结构图

7783-70-2
SMILES: F[Sb](F)(F)(F)F

化学属性

Mol. FormulaSbF5
Mol. Weight216.75
Vapor Density2.2 (vs air)
Boiling Point148-150 °C(lit.)
Vapor Pressure10 mmHg ( 25 °C)
Density2.993 g/mL at 25 °C(lit.)
Melting Point7 °C (lit.)
TSCAYes
Flash Point149.5°C
Solubility溶于无水乙醇。

别名和识别编码

Chemical NameAntimony(V) Fluoride
Synonym ANTIMONY PENTAFLUORIDE ANTIMONY(V) FLUORIDE ANTIMONY(V) FLUORIDE, 50 WT. % ON GRAPHI TE ANTIMONY(V) FLUORIDE, 99.99% Antimon(V)-fluorid Antimonpentafluorid Antimony (V) fluoride Antimony fluoride Antimony fluoride (SbF5) Antimony pentafluoride Antimony pentafluoride, 99.5+% Antimony(V) fluoride Antimony(V) pentafluoride Antimony(V)fluoride,98% AntimonyPentafluride Antimonyfl Antimonyfluoride2 Antimonyfluorideingraphitegraybluesolid Pentafluoroantimony SbF5 SbF5 cpd antimony (V) fluoride antimony pentafluoride antimony(v) fluoride on graphite antimony(v)pentafluoride antimonyfluoride(sbf5) {} {} {u
MDL NumberMFCD00011219
CAS Number7783-70-2
PubChem Substance ID24557
EC Number232-021-8
Chemical Name Translation氟化锑(V)
Merck Number13,702
Wiswesser Line Notation.SB..F5
LabNetwork Molecule IDLN02144553
InChIInChI=1S/5FH.Sb/h5*1H;/q;;;;;+5/p-5
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分类

  • {SNA} Antimony, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts
  • {SNA} Antimony Catalysts, Antimony Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis,

相关文献及参考

  • Short: III/20c Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zr ... Bi. Diagrams, Structure formulas, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20c Year: 1989 Keyword: NQR ISBN: 3-540-18490-2 ISBN: 978-3-540-18490-4 Internet Resource: DOI:10.1007/b35374 RefComment: 562 figs., IX,802 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312
  • P301+P312+P330
  • P301+P330+P331
  • P302+P352
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Signal word Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSCC5800000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupII
UN Number UN1732 UN 2923 8/PG 2
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R51/53
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R35 Causes severe burns 会导致严重灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
Storage condition Moisture Sensitive
Hazard Codes T,O,C,N,Xn Xn,N
Hazard Class8
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 mg/m3
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 35(7),25,1970

其他信息

  • Hazard Note:Corrosive/Oxidising agent
  • 蒸气密度:2.2 (vs air)
  • 五氟化锑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 174430250 五氟化锑 Antimony pentafluoride 99.5+% 25 GR 1979元 2010/06/21 174431000 五氟化锑 Antimony pentafluoride 99.5+% 100 GR 6397元 2010/05/25 33484 氟化锑, 98% Antimony(V) fluoride, 98% 100g 6104元
  • F:10
  • 毒性分级:高毒
  • 职业标准:TWA 0.5 毫克(锑)/立方米; STEL 2.5 毫克(锑)/立方米
  • 类别:腐蚀物品
  • Sigma Aldrich:7783-70-2(sigmaaldrich)
  • Acros Organics:五氟化锑 Antimony pentafluoride, 99.5+%(7783-70-2)
  • 灭火剂:干砂、二氧化碳
  • 储运特性:库房通风低温干燥; 与有机物分开存放
  • 急性毒性:吸入-小鼠 LC50: 270 毫克/立方米
  • 爆炸物危险特性:与磷酸盐反应激烈
  • 可燃性危险特性:遇水分解产腐蚀氟化氢气体, 产生氢氟酸; 遇易燃物易燃;库房通风低温干燥; 与食品原料分开存放干粉,泡沫,沙土,二氧化碳, 雾状水可燃; 燃烧产生有毒氟化物和锑化物烟雾
  • MSDS 信息:五氟化锑(7783-70-2).msds
  • 外观性质:无色油状液体。
  • Alfa Aesar:氟化锑,98% Antimony(V) fluoride, 98%(7783-70-2)
  • MOL 文件:7783-70-2.mol
  • 蒸气压:10 mm Hg ( 25 °C)
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Antimony - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Antimony - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Aluminum

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