乙酰丙酮钼 乙酰丙酮钼
CAS 17524-05-9 MFCD00011506
化学结构图
SMILES: CC(=O)/C=C(/C)\O[Mo](=O)(=O)O/C(/C)=C\C(C)=O
化学属性
| Mol. Formula | C10H14MoO6 |
|---|---|
| Mol. Weight | 326.18 |
| TSCA | No |
| Melting Point | 184 |
| Solubility | 8.52 G/100 ML (20 ºC) |
| Density | 1.64 |
别名和识别编码
| Chemical Name | 乙酰丙酮钼 |
|---|---|
| MDL Number | MFCD00011506 |
| Synonym | Bis(acetylacetonato)dioxomolybdenum(VI) Molybdenyl acetylacetonate MoO2(acac)2 Molybdenum dioxydiacetylacetonate 乙酰丙酮钼 Molybdenum diacetylacetonate dioxide Molybdenum dioxide bis(acetylacetonate) |
| EC Number | 241-522-0 |
| CAS Number | 17524-05-9 |
| PubChem Substance ID | 87572516 |
| Reaxys-RN | 4141174 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 乙酰丙酮钼 |
| InChIKey | SKMUJBBRXZPAJY-UZUXQKAQSA-L |
| LabNetwork Molecule ID | LN01373463 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Molybdenum Catalysts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Molybdenum
产品应用
- 构成一种功能性的复合物用于研究钼血清转移酶（oxotransferase molybdenum）
相关文献及参考
- Mild catalyst for the deprotection of acetals in high yield: Synth. Commun., 25, 2529 (1995).
- In the presence of a phase-transfer catalyst, catalyzes the high yield oxidation of secondary alcohols to ketones with sodium percarbonate in acetonitrile or 1,2-dichloroethane. Primary alcohols give moderate to good yields of aldehydes: Synlett, 439 (1996).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R22 Harmful if swallowed 吞咽有害
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P312
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P302+P352+P312+P362+P364
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H319 Causes serious eye irritation 严重刺激眼睛
- H302+H312+H332
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