CAS 75-35-4 MFCD00011653-1,1-Dichloroethene 1，1-二氯乙烯 -LabNovo

1,1-Dichloroethene 1，1-二氯乙烯

CAS 75-35-4 MFCD00011653

化学结构图

SMILES: C=C(Cl)Cl

化学属性

Mol. Formula	C₂H₂Cl₂
Mol. Weight	96.94
Autoignition Point	968 °F
Vapor Density	3.46 (vs air)
Boiling Point	31.7°C
Vapor Pressure	9.68 psi ( 20 °C)
Density	1.213 g/mL at 20 °C(lit.)
Melting Point
Refractive index	1.4249
Flash Point	-25°(-13°F)
TSCA	Yes
Solubility	不溶于水。
Stability	对光敏感

别名和识别编码

Chemical Name	1,1-Dichloroethene
Synonym	1'1-Dichlorethen 1'1-Dichlorethylen 1,1-DCE 1,1-DICHLOROETHENE 1,1-DICHLOROETHYLENE 1,1-Dce 1,1-Dichlorethen 1,1-Dichlorethylen 1,1-Dichloroethene 1,1-Dichloroethene (stabilized with MEHQ) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Ethylene, 1,1-dichl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Ethene,1,1-dichloro- {} {} {} {} {} {} {} {} {} {uni_hamburg} Ethene, 1,1-dichloro- {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Diofan A 565S {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Chlorure de vinylidene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} CH2=CCl2 {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 1，1-二氯乙烯 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00011653
CAS Number	75-35-4
Beilstein Registry Number	1733365
PubChem Substance ID	6366
EC Number	200-864-0
Merck Number	14,9996
Reaxys-RN	1733365
Chemical Name Translation	1，1-二氯乙烯
Wiswesser Line Notation	GYGU1
LabNetwork Molecule ID	LN00196141
InChI	InChI=1S/C2H2Cl2/c1-2(3)4/h1H2

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品牌质保精细包装现货库存一流品牌服务

产品应用

校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H332 Harmful if inhaled 吸入有害
H315 Causes skin irritation 会刺激皮肤
H301 Toxic if swallowed 吞食有毒
H351 Suspected of causing cancer 怀疑致癌
H319 Causes serious eye irritation 严重刺激眼睛
H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

RTECSKV9275000

Precautionary statements

P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P337+P313
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P403+P233
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P303+P361+P353
P201 Obtain special instructions before use. 使用前获取专门指示。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P304+P340
P308+P313
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P233 Keep container tightly closed. ?保持容器密闭。
P304+P340+P312
P305+P351+P338+P337+P313
P308+P311
P241+P242+P243
P305+P351+P338
P405 Store locked up. 上锁保管。

Signal word Danger

Packing GroupII

UN Number UN 1303 3/PG 1 1303 UN1303 1230

Risk Statements

R12 Extremely flammable 极端易燃
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R20 Harmful by inhalation 吸入有害
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R11 Highly flammable 非常易燃

Safety Statements

S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
S29 Do not empty into drains 不要排入下水道；
S7 Keep container tightly closed 保存在严格密闭容器中；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Storage condition 0-10 0-10°C 2-8°C 4 Light Sensitive 储存温度 2-8°C 储存温度2-8℃ 密封2-8°C避光保存

Hazard Codes F+,Xn F+,Xn,T,F F+;Xn

Hazard Class3/6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 ppm/4H/52W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Kidney, Ureter, Bladder - Kidney tumors
   Blood - leukemia
REFERENCE :
   MELAAD Medicina del Lavoro.  Industrial Med

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4840 mg/kg
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Skin and Appendages - tumors
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 63,1433,1979

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 55 ppm/6H/28W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Skin and Appendages - tumors
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 7,909,1981

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 150 ppm/4H/52W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
   Liver - tumors
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/y

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 5750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJPPAL Quarterly Journal of Pharmacy & Pharmacology.  (London, UK)  V.2-21,
   1929-48.  For publisher information, see JPPMAB.  Volume(issue)/page/ye

{hazar

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   QJPPAL Quarterly Journal of Pharmacy & Pharmacology.  (London, UK)  V.2-21,
   1929-48.  For publisher information, see JPPMAB.  Volume(issue)/page/year:
   7,205,1934

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 194 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   37,411,1978

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 25 ppm
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   CHINAG Chemistry and Industry (London).  (Royal Soc. of Chemistry,
   Distribution Centre, Blackhorse Rd., Letchworth, Herts SG6 1HN, UK)  V.1-
   1923-  Volume(issue)/page/year: (11),463,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill

{hazard_com

TYPE OF TEST            : Unscheduled DNA synthesis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 36,199,1985

TYPE OF TEST            : Specific locus test
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 160 ppm/48H (Continuous)
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   17,122,1991

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 50 ppm
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   53,357,1980

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 30 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,179,1981

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 75 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 187,157,1987

TYPE OF TEST            : Host-mediated assay
TEST SYSTEM             : Rodent - mouse Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 400 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 160 ppm/7H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   49,189,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 200 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - other measures of fertility
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   49,189,1979

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 55 ppm/6H
SEX/DURATION            : female 55 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - female fertility index (e.g. # females pregnant
   per # sperm positive females; # females pregnant per # females mated)
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 3,965,1977

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE

Restrict 危险品

其他信息

Acros Organics:偏二氯乙烯 Vinylidene chloride, stabilized, 99.90%(75-35-4)
蒸气压:9.68 psi ( 20 °C)
Alfa Aesar:氯化亚乙烯,99%,stab.with200ppm4-methoxyphenol Vinylidene chloride, 99%, stab. with 200 ppm 4-methoxyphenol(75-35-4)
外观性质:无色液体，带有不愉快气味。
用途四:用作辅聚剂、粘合剂和用于有机合成。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
爆炸物危险特性:与空气混合可爆
1，1-二氯乙烯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 K9500001 1.1-二氯乙烯（阴凉） 250ml 320元 2011/08/23 K9500002 1.1-二氯乙烯（阴凉）¤ L 750元 2011/04/16 S0620 1,1-二氯乙烯(1mg/ml的甲醇溶液)[用于水分析] 1,1-Dichloroethylene (1m
方法二:工业制法由氯乙烯和氯气反应先制成1,1,2-三氯乙烷，然后用10%氢氧化钙水溶
1，1-二氯乙烯价格(试剂级):更新日期产品编号产品名称包装价格
用途三:1,1-二氯乙烯为基础（至少含80%）的共聚物，可制得具有耐火性的偏氯纶。1,1-二
方法一:工业上的制备方法是将氯乙烯与氯气在80～90℃以铁屑为催化剂制得1，1，2-三氯乙烷，然后将三氯乙烷与氢氧化钠在80～90℃进行反应，脱去一分子氯化氢即得粗偏二氯乙烯，再经蒸馏即得成品。反应方程式：CH 2 ＝CHCl[Cl 2 ]→[FeCl 3 ]CH 2 Cl—CHCl 2 [NaOH]→CH 2 ＝CCl 2
类别:易燃液体
MSDS 信息:1,1-二氯乙烯(75-35-4).msds
挥发性有机化合物(VOCs)单组分标准液
TCI Shanghai:1,1-二氯乙烯(1mg/ml的甲醇溶液)[用于水分析] 1,1-Dichloroethylene (1mg/ml in Methanol) [for Water Analysis](75-35-4)
职业标准:TWA 20 毫克/ 立方
可燃性危险特性:遇明火、高温、氧化剂易燃; 高热分解有毒氯化物气体
Sigma Aldrich:75-35-4(sigmaaldrich)
MOL 文件:75-35-4.mol
用途三:1,1-二氯乙烯为基础（至少含80%）的共聚物，可制得具有耐火性的偏氯纶。1,1-二氯乙烯与丙烯腈、丁二烯、丙烯酸酯、苯乙烯等共聚，可制得各种合成树脂。偏二氯
敏感性:Light Sensitive
用途三:1,1-二氯乙烯为基础（至少含80%）的共聚物，可制得具有耐火性的偏氯纶。1,1-二氯乙烯与丙烯腈、丁二烯、丙烯酸酯、苯乙烯等共聚，可制得各种合成树脂。偏二氯乙烯树脂可加工成纤维或薄膜，并可用于纸或塑料薄膜的表面涂层。聚偏二氯乙烯纤维可用于生产织物、帐篷、防虫网、汽车坐垫等。聚偏二氯乙烯薄膜的透气性、透湿性比其它塑料薄膜小，适用于食品包装。与甲基丙烯酸、甲基丙烯酸甲酯等
用途二:偏二氯乙烯即1，1-二氯乙烯，是偏二氯乙烯法制备二氯菊酸甲酯的中间体。该产品除能本身聚合外，还能与氯乙烯、丙烯腈、丁二烯、甲基丙烯酸、甲基丙烯酸甲酯等多种
用途一:主要用于生产偏氯乙烯-氯乙烯、偏氯乙烯-丙烯腈和偏氯乙烯-丙烯酸酯类共聚物
上游原料:盐酸 --> 氯 --> 铁屑 --> 1,1,2-三氯乙烷
用途二:偏二氯乙烯即1，1-二氯乙烯，是偏二氯乙烯法制备二氯菊酸甲酯的中间体。该产品除能本身聚合外，还能与氯乙烯、丙烯腈、丁二烯、甲

1,1-Dichloroethene 1，1-二氯乙烯

CAS 75-35-4 MFCD00011653

化学结构图

化学属性

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相关文献及参考

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化学结构图

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别名和识别编码

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相关产品推荐

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