7,7,8,8-Tetracyanoquinodimethane 7,7,8,8-四氰基对苯二醌二甲烷

CAS 1518-16-7 MFCD00011664

化学结构图

1518-16-7
SMILES: N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1

化学属性

Mol. FormulaC12H4N4
Mol. Weight204.19
Density1.358
Melting Point287-289°C
TSCAYes
Solubility不溶
Boiling Point254.677 °C at 760 mmHg

别名和识别编码

Chemical Name7,7,8,8-Tetracyanoquinodimethane
Synonym 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononit
CAS Number1518-16-7
EC Number216-174-8
Beilstein Registry Number611604
MDL NumberMFCD00011664
PubChem Substance ID73697
Reaxys-RN611604
Chemical Name Translation7,7,8,8-四氰基对苯二醌二甲烷
InChIKeyPCCVSPMFGIFTHU-UHFFFAOYSA-N
Wiswesser Line NotationL6Y DYJ AUYCN&CN DUYCN&CN
LabNetwork Molecule IDLN00196283
InChIInChI=1S/C12H4N4/c13-5-11(6-14)9-1-2-10(4-3-9)12(7-15)8-16/h1-4H
Canonical SMILESN#C/C(C#N)=C1C=C/C(C=C/1)=C(C#N)\C#N
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Bioactive Small Molecules, Hole Injection Layer (HIL) Materials, Hole Transport (HT) & Hole Injection Layer (HIL) Materials, Materials Science, NLO Chromophores and Intermediates, Non-Linear Optical (NLO) Materials, OLED and PLED Materials, Organic Field Effect Transistor (OFET) Materials, Organic and Printed Electronics, Photonic and Optical Materials, T, n-Type Organic Semiconductors, n-Type Small Molecules, 细胞生物学
  • {SNA} Bioactive Small Molecules, Cell Biology, Hole Injection Layer (HIL) Materials, Hole Transport (HT) & Hole Injection Layer (HIL) Materials, Materials Science, NLO Chromophores and Intermediates, Non-Linear Optical (NLO) Materials,
  • {SNA} Hole Injection Layer (HIL) Materials, Hole Transport (HT)

产品应用

  • 用于形成电荷转移超导体的电子受体分子。

相关文献及参考

  • For a review of the differences between "metallic" and "non-metallic" salts of TCNQ, see: Acc. Chem. Res., 12, 79 (1979).
  • Effective catalyst for the ɑ-chlorination of carboxylic acids using chlorosulfonic acid; the presence of TCNQ suppresses competing free-radical chlorination: J. Org. Chem., 48, 1364 (1983).
  • Short: III/20a
  • Electron-acceptor, forming stable radical anions: J. Am. Chem. Soc., 82, 6408 (1960); 84, 3370, 3374 (1962).
  • Forms charge-transfer complexes with electron-rich donors: J. Am. Chem. Soc., 95, 948 (1973).
  • Short: III/5a
  • Short: III/41E

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P312
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P312
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSGU4850000
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Packing GroupIII
UN Number 3439
Hazard Codes 6.1 T Xn Xn,Xi
Hazard Class6.1
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00796

其他信息

  • 图谱信息:7,7,8,8-四氰基对苯二醌二甲烷(1518-16-7)红外图谱(IR2) 7,7,8,8-四氰基对苯二醌二甲烷(1518-16-7)质谱(MS) 7,7,8,8-四氰基对苯二醌二甲烷(1518-16-7)红外图谱(IR1)
  • 7,7,8,8-四氰基对苯二醌二甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0078 7,7,8,8-四氰基对醌二甲烷 7,7,8,8-Tetracyanoquinodimethane 25G 2360元 2014/06/02 T0078 7,7,8,8-四氰基对醌二甲烷 7,7,8,8-Tetracyanoquinodimethane 5G 817元 2010/06/21 169360100 7,7,8,8-四氰基对苯二醌二甲烷 7,7,8,8-Tetracyanoquinodimethane 98% 10 GR 1225元
  • Acros Organics:7,7,8,8-四氰基对醌二甲烷 7,7,8,8-Tetracyanoquinodimethane, 98%(1518-16-7)
  • 7,7,8,8-四氰基对苯二醌二甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0078 7,7,8,8-四氰基对醌二甲烷 7,7,8,8-Tetracyanoquinodimethane 25G 1940元 2011/04/16 T0078 7,7,8,8-四氰基对醌二甲烷 7,7,8,8-Tetracyanoquinodimethane 5G 674元 2010/06/21 169360100 7,7,8,8-四氰基对苯二醌二甲烷 7,7,8,8-Tetracyanoquinodimethane 98% 10 GR 1225元
  • 海关编码:29269095
  • Hazard Note:Irritant
  • MOL 文件:1518-16-7.mol
  • Sigma Aldrich:1518-16-7(sigmaaldrich)
  • MSDS 信息:7,7,8,8-Tetracyanoquinodimethane(1518-16-7).msds
  • Alfa Aesar:7,7,8,8-四氰基对二次甲基苯醌,98% 7,7,8,8-Tetracyanoquinodimethane, 98%(1518-16-7)
  • TCI Shanghai:7,7,8,8-四氰基醌二甲烷 7,7,8,8-Tetracyanoquinodimethane,>;98.0%(T)(1518-16-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Cyanides/Nitriles - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Cyanides/Nitriles - Nitrogen Compounds
  6. C10 to C27 - Cyanides/Nitriles
  1. Materials Science 材料科学
  2. Products for Organic & Printed Electronics Research
  3. OLED and PLED Materials - Organic and Printed Electronics
  4. Hole Transport (HT) & Hole Injection Layer (HIL) Materials - OLED and PLED Materials
  5. Hole Injection Layer (HIL) Materials - Hole Transport (HT) & Hole Injection Layer (HIL) Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Cyanides/Nitriles
  6. C1 to C5
  1. Materials Science 材料科学
  2. Charge Transfer Complexes for Organic Metals

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