1,10-Phenanthroline 邻菲罗啉

CAS 66-71-7 MFCD00011678

化学结构图

66-71-7
SMILES: c1cnc2c(c1)ccc1cccnc12

化学属性

Mol. FormulaC12H8N2
Mol. Weight180.21
Melting Point114-117
TSCAYes
Boiling Point>330°
Solubility溶于醇和丙酮。
Flash Point>330°C
Appearance 一水物为白色结晶性粉末。熔点93-94℃，无水物熔点为117℃，溶于300份水，70份苯，溶于醇和丙酮。
Stability对湿度敏感

别名和识别编码

Chemical Name1,10-Phenanthroline
CAS Number66-71-7
Alfabeta NamePHENANTHROLINE 110-,
MDL NumberMFCD00011678
Synonym ORTHOPHENANTHROLINE 1,10-Phenanthroline Base, 38% 1,10 PHENANTHROLINE BASE 3 8% 无水 1,10邻二的氮杂菲, 99% 邻菲罗啉 o-Phenanthroline monohydrate Activ-8 in hexylene glycol 1,10-Phenanthroline anhydrous(o-phenanthroline, phenantholine) beta-Phenanthroline 邻菲罗啉, 1,10-菲罗啉 1,10-Fenanthrolin 1,10-菲咯啉 1,10-Phenanthroline amhydrous O-PHENANTHROLINE 1,10-邻二氮杂菲 1,10-PhenanthrolineAnhydrous97%Min 1,10-PHENANTHROLINE R. G., REAG. ACS, RE DOX INDICATOR 盐酸邻菲罗啉 无水 1,10邻二的氮杂菲 Solution forms containing 1,10-phenanthroline 菲羅琳 鄰啡啉 邻菲罗啉;邻啡啰啉;1,10-菲啰啉,邻二氮杂菲;2,9-二甲基啉菲罗啉;新铜试剂 邻菲咯啉 AKOS 92891 1,10-菲罗啉 1,10-Phenanthroline,97% 1,10-邻二氮杂菲(无水) Orthophenanthroline 1,10-菲啰啉 o-Phenanthroline 1,10-菲咯啉(无水) 1,10-PHENANTHROLINE 4,5-Diazaphenanthrene 1,10-Phenanthroline,anhydrous,99% 1,10-二氮杂菲 1,10-PHENANTHROLINE, 99+% 1,10-菲罗啉,盐酸盐 1,10-o-Phenanthroline 1,10-啡啉 4,5-Phenanthroline 1,10-菲罗啉/邻二氮杂菲
EC Number200-629-2
Merck Number7214
Beilstein Registry Number126461
PubChem Substance ID1318
Chemical Name Translation邻菲罗啉
InChIKeyDGEZNRSVGBDHLK-UHFFFAOYSA-N
Wiswesser Line NotationT B666 CN NNJ
LabNetwork Molecule IDLN00008170
Reaxys-RN4008096
InChIInChI=1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others
  • {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others, P
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Other Heterocyclic Building Blocks
  • {SNA} Bioactive Small Molecules, Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others, P, 细胞生物学

产品应用

  • 光谱测定金属和光谱分析CO2还原的常用配体。用于Cu(II)催化的有机硼酸的交联反应等等。

相关文献及参考

  • [2]. Zi-Qiang Liu, et al. The role of matrix metalloprotease (MMP) to the autolysis of sea cucumber (Stichopus japonicus). J Sci Food Agric. 2019 Oct;99(13):5752-5759.
  • For use as bidentate nitrogen ligands in Heck type reactions as an alternative to phosphine ligands, see: Synlett., 11, 871 (1992).
  • Indicator for titration of organolithium reagents, giving red charge-transfer complexes, and also in the titration of Grignard reagents: J. Organomet. Chem., 9, 165 (1967); Org. Synth. Coll., 9, 350, 653, 733 (1998).
  • Merck: 14,7214
  • Merck: 14,7214 Beilstein: 23,227
  • Reviews: 1,10-Phenanthroline: a versatile ligand: Chem. Soc. Rev., 23, 327 (1994); Coordination compounds as synthetic building blocks: Synlett, 1043 (2002).
  • [1]. Guan NanMu, et al. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Materials Chemistry and Physics Volume 86, Issue 1, 15 July 2004, Pages 59-68.
  • {MC

安全信息

Warnings IRRITANT
RTECSSF8300000
Safety Statements
Packing GroupIII
UN Number UN 2811 6.1/PG 3
Risk Statements
Storage condition 充氩储存 密封保存 Hygroscopic
WGK Germany3
GHS Symbol
Precautionary statements
  • P301+P310+P330
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H301 Toxic if swallowed 吞食有毒
Signal word
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T,N
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Kidney, Ureter, Bladder - other changes in urine composition
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 196,478,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 137,1,1962

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 5 mg/L
REFERENCE :
   ONCOBS Oncology.  (S. Karger AG, Postfach CH-4009 Basel, Switzerland) V.21- 
     1967-  Volume(issue)/page/year: 46,193,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 30 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 66,1755,1977

其他信息

  • 用途一:电镀添加剂，分析试剂。
  • 下游产品:1,10-邻二氮杂菲-5,6-二酮
  • 图谱信息:1,10-菲罗啉(66-71-7)质谱(MS)
  • Acros Organics:1,10-菲罗啉/邻二氮杂菲 1,10-Phenanthroline, 99+%(66-71-7)
  • 1,10-菲罗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 157530250 1,10-菲罗啉 1,10-Phenanthroline 99+% 25 GR 1095元 2010/06/21 157530050 1,10-菲罗啉 1,10-Phenanthroline 99+% 5 GR 329元 2010/06/21 157531000 1,10-菲罗啉 1,10-Phenanthroline 99+% 100 GR 3251元
  • 方法一:将邻苯二胺与甘油、硝基苯及浓硫酸一起加热，或改用8-氨基喹啉为原料，都可制备该品。
  • Alfa Aesar:无水1,10邻二的氮杂菲,99% 1,10-Phenanthroline, anhydrous, 99%(66-71-7)
  • 溶于醇和丙酮。
  • 海关编码:29339990
  • 上游原料:1,2-苯二胺 --> 8-氨基喹啉
  • 敏感性:Hygroscopic
  • MOL 文件:66-71-7.mol
  • MSDS 信息:o-Phenanthroline(66-71-7).msds
  • 检测方法:HPLC,NMR
  • Sigma Aldrich:66-71-7(sigmaaldrich)

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. P - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoquinolines 异喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. N-Containing - Others
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. N-Containing - Others
  1. Medical Research Areas
  2. Metabolism
  3. MMP  (基质金属蛋白酶)

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