1,1'-Dibenzyl-[4,4'-Bipyridine]-1,1'-Diium Chloride 1,1'-二苄基-4,4'-联吡啶二氯化物

CAS 1102-19-8 MFCD00011991

化学结构图

1102-19-8
SMILES: [Cl-].[Cl-].c1ccc(C[n+]2ccc(-c3cc[n+](Cc4ccccc4)cc3)cc2)cc1

化学属性

Mol. FormulaC24H22Cl2N2
Mol. Weight409.35
Melting Point262 °C

别名和识别编码

Chemical Name1,1'-Dibenzyl-[4,4'-Bipyridine]-1,1'-Diium Chloride
Synonym 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride {} {} {} {} {} {} {} {} {
MDL NumberMFCD00011991
PubChem Substance ID14195
Beilstein Registry Number3811585
CAS Number1102-19-8
EC Number214-158-5
Reaxys-RN3811585
Chemical Name Translation1,1'-二苄基-4,4'-联吡啶二氯化物
InChIKeyNLOIIDFMYPFJKP-UHFFFAOYSA-L
Wiswesser Line NotationT6KJ A1R& D- DT6KJ A1R &G 2
LabNetwork Molecule IDLN01741722
Canonical SMILESC1=CC=C(C=C1)C[N+]2=CC=C(C=C2)C3=CC=[N+](C=C3)CC4=CC=CC=C4.[Cl-].[Cl-]
InChIInChI=1S/C24H22N2.2ClH/c1-3-7-21(8-4-1)19-25-15-11-23(12-16-25)24-13-17-26(18-14-24)20-22-9-5-2-6-10-22;;/h1-18H,19-20H2;2*1H/q+2;;/p-2
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分类

  • {SNA} Materials Science, Organic and Printed Electronics, Photochromic and Thermochromic Dyes, Photonic and Optical Materials
  • {SNA} Organic and Printed Electronics, Photochromic and Thermochromic Dyes, Photonic and Optical Materials, 材料科学

相关文献及参考

  • Aldrich MSDS 1 , 185:C / Corp MSDS 1 (1), 405:D / FT-NMR 1 (3), 239:A / RegBook 1 (2), 2493:E / Sigma FT-IR 1 (2), 105:A / Structure Index 1 , 393:A:7
  • Beil. 23 ,V,8,35

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
RTECSDW1930000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word {} {} {} {} {TCI}
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7364 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Skin and Appendages - hair
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   45,234,1978

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 1,1'-二卞-4,4'-二吡啶二氯化物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2137 1,1'-二苄基-4,4'-二氯化二吡啶嗡水合物 1,1'-Dibenzyl-4,4'-bipyridinium Dichloride Hydrate 5G 2970元 2014/06/02 D2137 1,1'-二苄基-4,4'-二氯化二吡啶嗡水合物 1,1'-Dibenzyl-4,4'-bipyridinium Dichloride Hydrate 25G 8880元 2014/06/02 D2137 1,1'-二苄基-4,4'-二氯化二吡啶嗡水合物 1,1'-Dibenzyl-4,4'-bipyridinium Dichloride Hydrate 1G 1020元
  • F:3-10
  • MOL 文件:1102-19-8.mol
  • 图谱信息:1,1'-二卞-4,4'-二吡啶二氯化物(1102-19-8)红外图谱(IR1) 1,1'-二卞-4,4'-二吡啶二氯化物(1102-19-8)红外图谱(IR2) 1,1'-二卞-4,4'-二吡啶二氯化物(1102-19-8)质谱(MS)
  • TCI Shanghai:1,1'-二苄基-4,4'-二吡啶嗡二氯化物水合物 1,1'-Dibenzyl-4,4'-bipyridinium Dichloride Hydrate,>;98.0%(LC)(1102-19-8)
  • Sigma Aldrich:1102-19-8(sigmaaldrich)

系列性分类


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