2,4,6-Triphenylpyrylium tetrafluoroborate 2,4,6-三苯基吡喃四氟化硼盐

CAS 448-61-3 MFCD00012001

化学结构图

448-61-3
SMILES: F[B-](F)(F)F.c1ccc(-c2cc(-c3ccccc3)[o+]c(-c3ccccc3)c2)cc1

化学属性

Mol. FormulaC23H17BF4O
Mol. Weight396.19
Melting Point250-251 °C
TSCANo
Density1.0

别名和识别编码

Chemical Name2,4,6-Triphenylpyrylium tetrafluoroborate
MDL NumberMFCD00012001
CAS Number448-61-3
Beilstein Registry Number3586533
EC Number207-186-4
PubChem Substance ID9930615
Synonym 2,4,6-Triphenylpyrylium tetrafluoroborate {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetraflu
Chemical Name Translation2,4,6-三苯基吡喃四氟化硼盐
InChIKeyVQYPWMWEJGDSTF-UHFFFAOYSA-N
Wiswesser Line NotationT6OJ BR& DR& FR &.B-F4 &3/19
LabNetwork Molecule IDLN00201404
InChIInChI=1S/C23H17O.BF4/c1-4-10-18(11-5-1)21-16-22(19-12-6-2-7-13-19)24-23(17-21)20-14-8-3-9-15-20;2-1(3,4)5/h1-17H;/q+1;-1
Canonical SMILESFB(F)F.C1(C2=CC=CC=C2)=CC(C3=CC=CC=C3)=CC(C4=CC=CC=C4)=[O+]1.[F-]
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Others
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Other Heterocyclic Building Blocks

相关文献及参考

  • Amines react with pyrylium salts to give N-alkylpyridinium salts. Since the pyridine can be displaced by a variety of nucleophiles, the result is that the amine has been converted to a useful alkylating species: J. Chem. Soc., Perkin 1, 418 (1979). Reviews: Tetrahedron, 36, 679 (1980); Angew. Chem. Int. Ed., 23, 420 (1984); Russ. Chem. Rev., 51, 469 (1982):
  • For a review on use as an electron-transfer photosensitizer, see: Chem. Rev., 94, 1063 (1994).

安全信息

RTECSUZ1370000
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02142

其他信息

  • 图谱信息:2,4,6-三苯基吡喃四氟化硼盐(448-61-3)核磁图( 1 HNMR)
  • 2,4,6-三苯基吡喃四氟化硼盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 389290250 2,4,6-三苯基吡喃四氟化硼盐 2,4,6-Triphenylpyrylium tetrafluoroborate 97+% 25 GR 1349元 2010/06/21 389290050 2,4,6-三苯基吡喃四氟化硼盐 2,4,6-Triphenylpyrylium tetrafluoroborate 97+% 5 GR 341元 2010/05/25 A18217 2,4,6-三苯基吡喃四氟硼酸盐, 97% 2,4,6-Triphenylpyrylium tetrafluoroborate, 97% 25g 1302元
  • MOL 文件:448-61-3.mol
  • Alfa Aesar:2,4,6-三苯基吡喃四氟硼酸盐,97% 2,4,6-Triphenylpyrylium tetrafluoroborate, 97%(448-61-3)
  • Acros Organics:2,4,6-Triphenylpyrylium tetrafluoroborate, 97+%(448-61-3)
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:448-61-3(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrans 派兰斯
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. O-Containing - Others
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. N-Containing
  1. Photocatalyst

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