Bis(1,5-cyclooctadiene)diiridium(I) dichloride 双(1,5-环辛二烯)氯化铱(I)二聚体
CAS 12112-67-3 MFCD00012414
化学结构图
SMILES: C1=CCCC=CCC1.C1=CCCC=CCC1.Cl[Ir].Cl[Ir]
化学属性
| Solubility | Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol. |
|---|---|
| TSCA | No |
| Density | 1.422 |
| Mol. Formula | [IrCl(C8H12)]2 |
| Mol. Weight | 672 |
| Appearance | red to orange pwdr. |
| Melting Point | 205 |
| Redox | Reduction |
别名和识别编码
| Chemical Name | Bis(1,5-cyclooctadiene)diiridium(I) dichloride |
|---|---|
| Synonym | 1, 1,5-辛二烯氯化铱二聚体 BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC& Bis(1,5-cyclooctadiene)diiridium(I) dichloride CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR) Chlor-(1,5-cyclooctadien)-iridium(I) Dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9% Chloro(1,5-cyclooctadiene)iridium(I)dimere Chloro-1,5-cyclooctadieneiridium(I)dimer,99% DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM IRIDIUM I CYCLOOCTADIENE CHLORIDE [Ir(cod)Cl]2 di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium 双(1,5-环辛二烯)diiridium(一)二氯化 氯代-1,5-环戊二烯铱二聚体 |
| EC Number | 235-170-7 |
| PubChem Substance ID | 87560730 |
| Beilstein Registry Number | 14372408 |
| Chemical Name Translation | 双(1,5-环辛二烯)氯化铱(I)二聚体 |
| Reaxys-RN | 14372408 |
| InChIKey | ILRJMVBVICHYPJ-UHFFFAOYSA-L |
| LabNetwork Molecule ID | LN00197889 |
| MDL Number | MFCD00012414 |
| CAS Number | 12112-67-3 |
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分类
- {uni_hamburg}
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts
相关文献及参考
- In the presence of a phosphite, catalyzes displacements by carbon nucleophiles at the more substituted position in allylic systems: Angew Chem. Int. Ed., 36, 263 (1997); J. Am. Chem. Soc., 120, 8647 (1998).
- With catalytic amounts of dppp (1,3-Bis(diphenylphosphino)propane, A12931) and Cs2CO3, a transfer hydrogenation system with 2-propanol as the H source can reduce both olefinic double bonds and carbonyl groups; for ɑß-unsaturated ketones, selective reduction to saturated ketones can be achieved: J. Org. Chem., 66, 4710 (2001).
- Effective catalyst for the reaction of alcohols with vinyl acetate to give vinyl ethers: J. Am. Chem. Soc., 124, 1590 (2002).
- Catalyst for Miyaura and Hartwig's direct boronylation of arenes with Bis(pinacolato)diboron, L16088: J. Am. Chem. Soc., 124, 390 (2002):
- Short: III/10b
- Short: EINECS
- Catalyst precursor for asymmetric hydrogenation: Angew. Chem. Int. Ed., 37, 2897 (1998).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:12112-67-3.mol
- TSCA:No
- F:10
- 1,5-环辛二烯氯化铱二聚体价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C1807 (1,5-环辛二烯)氯化铱(I)二聚体 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 1G 2260元 2010/06/21 363962500 1,5-环辛二烯氯化铱二聚体 Chloro(1,5-cyclooctadiene)iridium(I) dimer 250 MG 1304元 2010/06/21 363960010 1,5-环辛二烯氯化铱二聚体 Chloro(1,5-cyclooctadiene)iridium(I) dimer 1 GR 3691元
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