N,N,N',N'-Tetramethyl-p-Phenylenediamine Dihydrochloride N,N,N,N-四甲基对苯二胺二盐酸盐

CAS 637-01-4 MFCD00012482

化学结构图

637-01-4
SMILES: CN(C)c1ccc(N(C)C)cc1.Cl.Cl

化学属性

Mol. FormulaC10H16N2.2HCl
Mol. Weight237
Melting Point220-224
TSCAYes
Flash Point110 ºC
Boiling Point260 ºC
SolubilitySoluble in DMSO (~1.7 mg/ml), water (50 mg/ml), and PBS (pH 7.2).,
Appearance powder
Stability对湿度和光线敏感

别名和识别编码

Chemical NameN,N,N',N'-Tetramethyl-p-Phenylenediamine Dihydrochloride
CAS Number637-01-4
Alfabeta NameTETRAMETHYLPHENYLENEDIAMINEDIHYDROCHLORIDE NNNNP---,,,''
MDL NumberMFCD00012482
Synonym N,N,N',N'-TETRAMETHYL-P-*PHENYLENEDIAMIN E DIHYDROCH 二盐酸N,N,N',N'-四甲基-1,4-苯二胺 N,N,N',N'-TETRAMETHYL-1,4-PHENYLENEDIAMINE DIHYDROCHLORIDE Wur 二盐酸四甲基对苯二胺 二盐酸四甲基对苯二胺(TMPD) 1,4-Benzenediamine,N,N,N’,N’-tetramethyl-,dihydrochloride WURSTER-REAGENT n,n,ni,ni-tetramethyl-p-phenylenediaminedihydrochloride N,NnTetramethyl-P-Phenylenediamine N,N,N',N'-TETRAMETHYL-1,4-BENZENEDIAMINE, DIHYDROCHLORIDE Wurster 试剂 p-phenylenediamine,n,n,n’,n’,tetramethyl-,dihydrochloride N'-四甲基-1,4-苯二胺二盐酸盐 Wurster’s reagent WURSTER'S REAGENT DIHYDROCHLORIDE 1,4-Bis(dimethylamino)benzene dihydrochloride N,N,N′,N′-四甲基对苯二胺 二盐酸盐
Beilstein Registry Number7442241
PubChem Substance ID71561
EC Number211-274-8
Reaxys-RN5132096
Chemical Name TranslationN,N,N,N-四甲基对苯二胺二盐酸盐
LabNetwork Molecule IDLN00119487
InChIInChI=1S/C10H16N2.2ClH/c1-11(2)9-5-7-10(8-6-9)12(3)4;;/h5-8H,1-4H3;2*1H
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分类

  • {SNA} Amine Salts, Building Blocks, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents TLC, Nitrogen Compounds, Organic Building Blocks, Osazones, TLC Reagents, S-Z, TLC Visualization (Staining) Reagents (alphabetic sort), TLC Visualization (Staining) Reagents (by application),
  • Amine Salts, Analytical Reagents, Analytical/Chromatography, Building Blocks, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents TLC, Nitrogen Compounds, Organic Building Blocks, Osazones, TLC Reagents, S-Z, TLC Visualization Reagents (alphabetic sort), TLC Visuali
  • {SNA} Core Bioreagents,

产品应用

  • An oxidizable compound

相关文献及参考

  • See previous entry.
  • Beilstein:13,74

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL, MOISTURE SENSITIVE
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P312+P362+P364
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at RT. Light Sensitive 产品在储存过程中颜色会变暗 储存温度2-8℃; 充氩保存; 产品在储存过程中颜色会变暗 充氩保存; 产品在储存过程中颜色会变暗
UN Number
Packing GroupIII
Hazard Class6.1(a)

其他信息

  • N,N,N′,N′-Tetramethyl-p-phenylenediamine dihydrochloride(TMPD) is an oxidizable compound that serves as a reducing co-substrate for heme peroxidases. TMPD undergoes one-electron oxidation by the heme peroxidase higher oxidation states (compounds I and II) producing a highly colored product that absorbs at 611 nm. Thus, the stoichiometry of oxidation is 2 moles of TMPD oxidized per mole of hydroperoxide reduced by the peroxidase. The extinction coefficient of the oxidized TMPD at 611 nm is 12,200.2 TMPD is also used for the detection of peroxidases on polyacrylamide gels.
  • color:off-white to gray
  • 上游原料:甲醇 --> 硫酸 --> 氯化钠 --> 丙酮 --> 无水氯化钙 --> 氯化亚铜 --> 溴化钠 --> 对苯二胺盐酸盐
  • Sigma Aldrich:637-01-4(sigmaaldrich)
  • F:8
  • 用途一:微生物测试试剂,用于需氧微生物细胞色素氧化酶阳性反应的分类。通常用1%的N,N,N',N'-四甲基-1,4-苯二胺二盐酸盐水溶液。
  • MOL 文件:637-01-4.mol
  • Acros Organics:四甲基对苯二胺二盐酸盐 N,N,N',N'-Tetramethyl-p-phenylenediaminedihydrochloride,99%(637-01-4)
  • N,N,N',N'-四甲基对苯二胺二盐酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A8789001 二盐酸四甲基对苯二胺 5g 532元 2011/08/23 30177032 二盐酸四甲基对苯二胺 5g 342元 2011/08/23 30176980 二盐酸四甲基对苯二胺 5g 520元
  • Alfa Aesar:N,N,N',N'-四甲基对苯二胺二盐酸盐,98+% N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride, 98+%(637-01-4)
  • MSDS 信息:N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride(637-01-4).msds
  • TCI Shanghai:N,N,N',N'-四甲基-1,4-苯二胺二盐酸盐 N,N,N',N'-Tetramethyl-1,4-phenylenediamine Dihydrochloride,>;98.0%(T)(637-01-4)
  • 海关编码:29215190
  • 图谱信息:N,N,N',N'-四甲基对苯二胺二盐酸盐(637-01-4)红外图谱(IR2) N,N,N',N'-四甲基对苯二胺二盐酸盐(637-01-4)红外图谱(IR1) N,N,N',N'-四甲基对苯二胺二盐酸盐(637-01-4)质谱(MS)
  • 敏感性:Light Sensitive

系列性分类


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