2-(Aminooxy)acetic acid hydrochloride (2:1) 羧甲基羟胺半盐酸盐

CAS 2921-14-4 MFCD00012955

化学结构图

2921-14-4
SMILES: Cl.NOCC(=O)O.NOCC(=O)O

化学属性

Mol. FormulaC4H11ClN2O6
Mol. Weight219
Melting Point156
Solubility分解
Stability对湿度敏感

别名和识别编码

Chemical Name2-(Aminooxy)acetic acid hydrochloride (2:1)
Synonym (AMINOOXY)ACETIC ACID hydrochloride( (Aminooxy)acetic acid hemihydrochloride, (Carboxymethoxy)amine hemihydrochloride, Hydroxylamine-O-acetic acid hemihydrochloride (Aminooxy)acetic Acid Hemihydrochloride, O-(Carboxymethyl)hydroxylamine Hemihydrochloride (氨氧基)乙酸 半盐酸盐 (羧基甲氧基)胺 半盐酸盐 羟胺-O-乙酸 半盐酸盐 2-AMINOOXY-ACETICACIHYDROCHLORIDE AMINOOXYACETIC ACID, HYDROCHLORIDE SA AOA盐酸盐;(氨氧基)乙酸半盐酸盐;O-羧甲基羟胺半盐酸盐;羟胺-O-乙酸 半盐酸盐 Carboxymethoxyamine·0.5hydrochloride O-(羧甲基)羟胺半盐酸盐 O-羧甲基羟胺半盐酸盐 bis[(aminooxy)acetic] acid hydrochloride 氨氧基乙酸盐/AOA盐酸盐/O-羧甲基羟胺半盐酸盐 盐酸羧甲氧基胺 羧甲氧基胺半盐酸盐
Beilstein Registry Number3680528
PubChem Substance ID2723609
CAS Number2921-14-4
EC Number220-862-3
MDL NumberMFCD00012955
Reaxys-RN3910577
Chemical Name Translation羧甲基羟胺半盐酸盐
LabNetwork Molecule IDLN00190753
InChIInChI=1S/2C2H5NO3.ClH/c2*3-6-1-2(4)5;/h2*1,3H2,(H,4,5);1H
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分类

  • {SNA} A to C, Aminotransferases, Biochemicals and Reagents, Building Blocks, Cancer Metabolism, Cell Biology, Chemical Synthesis, Enzyme Inhibitors, Enzyme Inhibitors by Enzyme, Enzymes, Inhibitors, and Substrates, Glutamine Metabolism and Oncogenesis, Hydroxylamines, Inhibitors and Activators of Glutamine Metabolic Pathways, Nitrogen Compounds, Organic Building Blocks, 癌症研究
  • {SNA} A to C, Aminotransferases, Biochemicals and Reagents, Building Blocks, Cancer Metabolism, Cancer Research, Cell Biology, Chemical Synthesis, Enzyme Inhib

产品应用

  • 用于往酮类化合物上引入酸性基团，能制备化学发光材料，如在酮类化合物上制备化学发光物质ABEI标记。也用于转氨基酶的抑制剂。

相关文献及参考

  • 1. Tetrahedron Lett. 34 , 4347, (1993)
  • 2. Farmaco 46 , 887, (1991) 摘要
  • Beil. 3 ,H,235
  • Aldrich MSDS 1 , 353:A / Corp MSDS 1 (1), 691:B / FT-IR 1 (1), 591:C / FT-IR 2 (1), 920:C / IR-Spectra (3), 352:A / IR-Spectra (2), 312:H / NMR-Reference 2 (1), 498:D / RegBook 1 (1), 659:L / Sigma FT-IR 1 (2), 275:A / Structure Index 1 , 98:A:1

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
RTECSAF3150000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 储存温度2-8℃

其他信息

  • 用途:有机合成中间体。
  • 生产方法:将O-羧甲基丙酮肟与盐酸反应得到。
  • 图谱信息:羧甲基羟胺半盐酸盐(2921-14-4)Raman光谱 羧甲基羟胺半盐酸盐(2921-14-4)红外图谱(IR2) 羧甲基羟胺半盐酸盐(2921-14-4)红外图谱(IR1) 羧甲基羟胺半盐酸盐(2921-14-4)质谱(MS) 羧甲基羟胺半盐酸盐(2921-14-4)核磁图( 1 HNMR)
  • F:3
  • EPA化学物质信息:Acetic acid, (aminooxy)-, hydrochloride (2:1)(2921-14-4)
  • 羧甲基羟胺半盐酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0205 羧基甲氧基胺半盐酸盐 Carboxymethoxylamine Hemihydrochloride 25G 1430元 2014/06/02 C0205 羧基甲氧基胺半盐酸盐 Carboxymethoxylamine Hemihydrochloride 500G 14550元 2010/06/21 108430025 羧甲基羟胺半盐酸盐 Carboxymethoxylamine hemihydrochloride 98% 2.5 GR 1494元
  • RTECS号:AF3150000
  • 水中分解，有吸湿性，能与醛类反应生成肪。
  • MOL 文件:2921-14-4.mol
  • 羧甲基羟胺半盐酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C0205 羧基甲氧基胺半盐酸盐 Carboxymethoxylamine Hemihydrochloride 25G 1180元 2011/04/16 C0205 羧基甲氧基胺半盐酸盐 Carboxymethoxylamine Hemihydrochloride 500G 12010元 2010/06/21 108430025 羧甲基羟胺半盐酸盐 Carboxymethoxylamine hemihydrochloride 98% 2.5 GR 1494元

系列性分类

  1. Life Science 生命科学
  2. Cancer Research
  3. Cancer Metabolism - Cancer Research
  4. Glutamine Metabolism and Oncogenesis - Cancer Metabolism
  5. Inhibitors and Activators of Glutamine Metabolic Pathways - Glutamine Metabolism and Oncogenesis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydroxylamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Hydroxylamines
  1. Functional Group 官能团索引
  2. hydroxylamine
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Enzymes, Inhibitors, and Substrates
  4. Enzyme Inhibitors
  5. Enzyme Inhibitors by Enzyme
  6. Aminopeptidase N

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