Thimerosal 硫柳汞钠

CAS 54-64-8 MFCD00013062

化学结构图

54-64-8
SMILES: [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O

化学属性

Mol. FormulaC9H9HgNaO2S
Mol. Weight405
Melting Point232-233
Solubility1 G/ML (20 ºC)
Stability对光敏感
Flash Point250 °C
Appearance 为乳白至微黄色结晶性粉末；稍有特殊臭，微有引湿性。遇光易变质。1％水溶液pH6—8。易溶于水、乙醇，不溶于乙醚和苯。

别名和识别编码

Chemical NameThimerosal
Synonym Elicide 乙汞硫水杨酸钠盐 2-(ETHYLMERCURIOMERCAPTO)BENZONIC ACID SODIUM SALT ((o-carboxyphenyl)thio)ethylmercurysodiumsalt MERTHIOLA 乙基噻吩酸钠盐/硫柳汞钠/硫柳汞 Mercurothiolate Thiomersalate 硫柳汞钠 Merzonin Merfamin Merthiolate sodium; Ethylmercurithiosalicylic acid sodium salt THIOMERSAL Mercury, ethyl(2-mercaptobenzoate-S)-, sodium salt ETHYL[SOD 硫柳汞,硫柳汞酸钠,乙汞硫水杨酸钠盐;Mercury-([o-carboxyphenyl]thio)ethyl钠盐;乙基噻吩酸钠盐;乙汞硫柳酸钠 SODIUM ETHYLMERCURITHIOSALICYLATE MERTHIOLATE THIMEROSAL SOLUTION 硫柳汞酸钠 Ethyl (sodium o-mercaptobenzoato)mercury MERCURY-[(O-CARBOXYPHENYL)THIO]ETHYL SODIUM SALT Merzonin sodium Thimerosal 硫柳汞,硫柳汞酸钠,乙 ((o-carboxyphenyl)thio)ethyl-mercursodiumsalt Mercury-([o-carboxyphenyl]thio)ethyl 钠盐 乙基噻吩酸 钠盐 乙汞硫柳酸钠 乙汞硫水杨酸 钠盐 ETHYLMERCURITHIOSALICYLIC ACID SODIUM SALT 乙汞硫水杨酸钠盐/硫柳汞钠 o-(Ethylmercurithio)benzoic acid sodium salt Sodium ethylmercuric ETHYL MERCURITHIOSALICYLIC ACID NA Ethyl(2-mercaptobenzoato-S)mercury sodium salt Ethylmerkurit ((o-Carboxyphenyl)thio)ethylmercury sodium salt Sodium merthiolate Mercurate(1-), ethyl(2-mercaptobenzoate(2-)-O,S)-, sodium salt {Chem Ethylmercurithiosalicylic acid sodium salt Mertorgan Merthiolate sodium 乙汞硫柳酸鈉 Thiomersal 硫柳汞; 硫柳汞酸钠; 乙汞硫水杨酸钠盐; Mercury-([o-carboxyphenyl]thio)ethyl钠盐;乙基噻吩酸钠盐; 乙汞硫柳酸钠 ethyl(2-mercaptobenzoate(2-)-o,s)-mercurate(1-sodiumsalt 2-(ETHYLMERCURIOMERCAPTO)BENZOIC ACID SODIUM SALT Sodium
CAS Number54-64-8
PubChem Substance ID24900257
EC Number200-210-4
Beilstein Registry Number8169555
MDL NumberMFCD00013062
Chemical Name Translation硫柳汞钠
Merck Number13,9389
Wiswesser Line NotationQVR BS-HG-2 &-NA-
LabNetwork Molecule IDLN01111949
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分类

  • Analytical Standards, Analytical/Chromatography, Antibiotics, Antibiotics A to Z, Antibiotics T-Z, Antibiotics by Application, Bactericides, Chromatography, Environmental Standards, Pesticides, Pesticides & Metabolites, Preservatives and Disinfectants
  • {SNA} Analytical Reagents, Analytical/Chromatography, Antibiotics,
  • {SNA} Analytical Standards,
  • {SNA} Analytical Standards, Chromatography, EP Standards, EP Standards S - T, Pharmaceutical Standards, Pharmacopeia Standards, 分析/色谱
  • {SA} Antibiotics, Antibiotics A to Z, Antibiotics T-Z, Antibiotics by Application,
  • {SNA} Analytical Standards,

产品应用

  • 是一种有效的消毒剂，可用于皮肤、黏膜的消毒，也用于药剂的防腐。制剂有酊剂，霜剂。

相关文献及参考

  • Merck:13,9389 Beilstein: 10,IV,272

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 6.1 T+,N T+,N,T
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P302+P350
  • P304+P340
Signal word Danger
RTECSOV8400000
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R50/53
UN Number 2025
Packing GroupIII
Storage condition 密封避光保存 Store at RT.
Hazard Class6.1(b)
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 104 mg/kg/1Y-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Reproductive - Tumorigenic effects - uterine tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 4,185,1971

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TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 83 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Lungs, Thorax, or Respiration - other changes
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
REFERENCE :
   JTCTDW Journal of Toxicology, Clinical Toxicology.  (Marcel Dekker, 270
   Madison Ave., New York, NY 10016)  V.19-    1982-  Volume(issue)/page/year:
   34,453,1996

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,290,1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCOC** Pesticide Chemicals Official Compendium, Association of the American
   Pesticide Control Officials, Inc., 1966.  (Topeka, KS)
   Volume(issue)/page/year: -,1130,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 98 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 4,185,1971

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 45 mg/kg
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   20,106,1992

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 900 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 287,47,1993

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 450 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 287,47,1993

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 45 mg/kg
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York,

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 9 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 287,57,1993

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 125 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 287,71,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Ocular
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 65 ug/kg
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   RIGAA3 Rinsho Ganka.  Clinical Ophthalmology.  (Igaku Shoin, 5-24-3 Hongo,
   Bunkyo-ku, Tokyo 113-91, Japan)  V.1-    1947-  Volume(issue)/page/year:
   26,631,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1300 mg/kg
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   AROPAW Archives of Ophthalmology (Chicago).  (AMA, 535 N. Dearborn St.,
   Chicago, IL 60610)  New series: V.1-44(3), 1929-50; V.64-    1960-
   Volume(issue)/page/year: 93,52,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Ocular
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 112 mg/kg
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   AROPAW Archives of Ophthalmology (Chicago).  (AMA, 535 N. Dearborn St.,
   Chicago, IL 60610)  New series: V.1-44(3), 1929-50; V.64-    1960-
   Volume(issue)/page/year: 93,52,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 130 mg/kg
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive -

其他信息

  • 职业标准:TWA 0.01 毫克 （汞）/立方米; STEL 0.03 毫克 （汞）/立方米
  • 上游原料:溴乙烷
  • Acros Organics:乙汞硫水杨酸钠盐/硫柳汞钠 Ethylmercurithiosalicylic acid, sodium salt, 97.0-101.0%(54-64-8)
  • 类别:农药
  • 毒性分级:高毒
  • 用途二:是一种有效的消毒剂，可用于皮肤、黏膜的消毒，也用于药剂的防腐。制剂有酊剂，霜剂。
  • F:8
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 可燃性危险特性:可燃, 火场排出含汞, 氮氧化物, 硫氧化物, 氧化钠辛辣刺激烟雾
  • 图谱信息:硫柳汞钠(54-64-8)红外图谱(IR2) 硫柳汞钠(54-64-8)红外图谱(IR1) 硫柳汞钠(54-64-8)核磁图( 13 CNMR)
  • 储运特性:库房低温, 通风, 干燥; 与食品原料分开存放
  • 有臭味，微有引湿性，遇光易变质。易溶于水、乙醇，不溶于乙醚及苯，在空气中稳定。
  • 急性毒性:口服- 大鼠 LD50 75 毫克/ 公斤; 口服- 小鼠 LD50: 81 毫克/公斤
  • 用途一:是一种有效的消毒剂,可用于皮肤、黏膜的消毒,也用于药剂的防腐。
  • 硫柳汞钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10013914 硫柳汞钠 25g 130元 2011/08/23 10013916 硫柳汞钠 100g 498元 2011/08/23 10013924 硫柳汞钠 25g 128.7元
  • Sigma Aldrich:54-64-8(sigmaaldrich)
  • MOL 文件:54-64-8.mol

系列性分类

  1. Life Science 生命科学
  2. Antibiotics 抗生素
  1. Life Science 生命科学
  2. Antibiotics 抗生素
  3. Antibiotics A to Z - Antibiotics
  4. Antibiotics T-Z - Antibiotics A to Z
  1. Life Science 生命科学
  2. Antibiotics 抗生素
  3. Antibiotics A to Z - Antibiotics
  4. Antibiotics T-Z - Antibiotics A to Z
  1. Life Science 生命科学
  2. Antibiotics 抗生素
  3. Antibiotics by Application - Antibiotics
  4. Preservatives and Disinfectants - Antibiotics by Application
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organomercury - Organometallic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Bactericides - Pesticides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Salts - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Functional Group 官能团索引
  2. carboxylic acid salt
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Antibiotics
  4. Antibiotics by Application
  5. Genetic Marker Selection
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Culture
  4. Reagents and Supplements
  5. Mycoplasma Detection

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