Dicyclohexylamine nitrite 亚硝酸二环己胺

CAS 3129-91-7 MFCD00013128

化学结构图

3129-91-7
SMILES: C1CCC(NC2CCCCC2)CC1.O=NO

化学属性

Mol. FormulaC12
Mol. Weight228
Vapor Pressure3.3 mmHg ( 25 °C)
Melting Point182-183 °C (dec.)(lit.)
Appearance 无色或淡黄色结晶粉末。 溶于水、甲醇和乙醇,不溶于醚。
Density0.91
SolubilityInsoluble in water.

别名和识别编码

Chemical NameDicyclohexylammonium Nitrite
Synonym Cyclohexanamine, N-cyclohexyl-, nitrite Cyclohexanamine,N-cyclohexyl-,nitrite DICYCLOHEXYLAMINE NITRITE DICYCLOHEXYLAMMONIUM NITRITE DODECAHYDRODIPHENYLAMINE NITRITE Dechan Diana Dichan Dichan 100 Dichau Dicyclohexyl ammonium nitrite Dicyclohexyl-ammonium nitrite Dicyclohexylamine nitrite Dicyclohexylaminenitrile Dicyclohexylaminonitrite Dicyclohexylammoniumnitrit Dicyklohexylamin nitrit Dicynit Dodecahydrophenylamine nitrite Dusitan dicyklohexylaminu Leukorrosin C N,N-DICYCLOHEXYLAMMONIUM NITRITE N-Cyclohexylcyclohexanamine nitrite N-环己基环己胺亚硝酸盐 N-环己基环己胺亚硝酸盐,二环己胺亚硝酸盐,二环己胺亚硝酸 NDA Nitrous acid dic
MDL NumberMFCD00013128
CAS Number3129-91-7
PubChem Substance ID241753
Beilstein Registry Number3711911
EC Number221-515-9
Reaxys-RN3711911
Chemical Name Translation亚硝酸二环己胺
Wiswesser Line NotationL6TJ AM- AL6TJ &..H..N-O2
LabNetwork Molecule IDLN00224678
InChIInChI=1S/C12H23N.HNO2/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;2-1-3/h11-13H,1-10H2;(H,2,3)
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; 2fragments
  • {SNA} Amine Salts, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 用作气相缓蚀剂。

相关文献及参考

  • Short: IV/20C
  • Short: EINECS
  • Short: IV/20B
  • Beilstein: 12,IV,22

安全信息

WGK Germany1
GHS Symbol
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H332 Harmful if inhaled 吸入有害
RTECSHY4200000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S15 Keep away from heat 远离热源;
  • S41 In case of fire and/or explosion do not breathe fumes 着火和/或爆炸时,不要吸入烟雾;
Hazard Codes Xn
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P312+P330
  • P301+P316
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P307+P311
  • P308+P311
  • P308+P316
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupIII
UN Number UN 2687 4.1/PG 3 2687
Hazard Class4.1
Storage condition 储存温度2-8℃
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2400 mg/kg/48W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2040 mg/kg/52W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,50,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 220 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/y

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 330 mg/kg
TOXIC EFFECTS :
   Liver - other changes
   Blood - normocytic anemia
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(11),51,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 375 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 37(2),102,1972

TYPE OF TEST            :

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 可燃性危险特性:受热放出有毒亚硝酸和氧化氮气体
  • Sigma Aldrich:3129-91-7(sigmaaldrich)
  • 毒性分级:中毒
  • 类别:有毒物品
  • TCI Shanghai:亚硝酸二环己胺 Dicyclohexylamine Nitrite,>;97.0%(T)(3129-91-7)
  • 职业标准:TWA 1 毫克/立方米; STEL 5 毫克/立方米
  • 蒸气压:3.3 mm Hg ( 25 °C)
  • MSDS 信息:Dicyclohexylammonium nitrite(3129-91-7).msds
  • 上游原料:十二氢二苯胺
  • 用途二:用作气相缓蚀剂。主要用于金属缓蚀保护和阻止金属锈蚀的继续进行。如用于汽车及汽车零件;减速机箱;内燃机;机床工具;刃具量具等,也可用于武器;雷达等设备的金属保护。气相缓蚀剂具有优良的性能,防锈期长,防锈效果好,复杂与简单的部件均适宜。但对黄铜;锡及其合金有腐蚀作用。
  • MOL 文件:3129-91-7.mol
  • 20℃的蒸气压1.33×10-2Pa。水中溶解度:水中3.9%,乙醇中9%,甲醇中23%。在碱性介质中稳定,在酸性介质中变为亚硝酸铵。热至175℃时分解并放出氨气。
  • 灭火剂:二氧化碳、砂土、泡沫、干粉、水
  • 图谱信息:亚硝酸二环己胺(3129-91-7)红外图谱(IR1) 亚硝酸二环己胺(3129-91-7)质谱(MS)
  • 亚硝酸二环己胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81006927 亚硝酸二环己胺 250g 62元 2011/04/16 D1392 亚硝酸二环己胺 Dicyclohexylamine Nitrite 500G 1080元 2011/04/16 D1392 亚硝酸二环己胺 Dicyclohexylamine Nitrite 25G 206元
  • 用途一:用作气相缓蚀剂。主要用于金属缓蚀保护和阻止金属锈蚀的继续进行。如用于汽车及汽车零件、减速机箱、内燃机、机床工具、刃具量具等,也可用于武器、雷达等设备的金属保护。气相缓蚀剂具有优良的性能,防锈期长,防锈效果好,复杂与简单的部件均适宜。但对黄铜、锡及其合金有腐蚀作用。
  • 方法一:由二环己胺与磷酸反应生成磷酸二环己胺,然后加入亚硝酸钠反应生成亚硝酸二环己胺:反应生成物经洗涤、干燥得成品。
  • 急性毒性:口服-小鼠 LDL0: 80 毫克/ 公斤

系列性分类


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