Palladium(II) Trifluoroacetate 三氟乙酸钯

CAS 42196-31-6 MFCD00013204

化学结构图

42196-31-6
SMILES: O=C(O[Pd]OC(=O)C(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC4F6O4Pd
Mol. Weight332
Melting Point210
TSCANo
Density1.422
RedoxReduction

别名和识别编码

Chemical NamePalladium(II) Trifluoroacetate
Synonym 2,7-DICHLORO-9-FLUORENONE, TECH., 90% PALLADIUM (II) TRIFLUOROACETATE 97+% PALLADIUM TRIFLUOROACETATE Palladium(II) trifluoroacetate, min. 97% Palladium(II)trifluoroacetate,min.97% Pd(TFA)2 Trifluoroacetic acid palladium(II) salt 三氟乙酸 钯(II) 盐
MDL NumberMFCD00013204
PubChem Substance ID2733347
CAS Number42196-31-6
Reaxys-RN15732764
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation三氟乙酸钯
LabNetwork Molecule IDLN00197814
InChIInChI=1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
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分类

  • {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Homogeneous Pd Catalysts, Material
  • {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Homogeneous Pd Catalysts, Micro/NanoElectronics, Palla

相关文献及参考

  • Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allyl­palladium(II)­ chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)­phosphine, L13329, has been found to give superior results to Palladium(II)­ acetate, 10516, or Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760, as a Pd source in Heck, Stille and Suzuki coupling reactions carried out in supercritical CO2: Tetrahedron Lett., 40, 2221 (1999).
  • Kato, K.; Motodate, S. et al. Angew. Chem. Int. Ed. Engl. 48 , 3326, (2009)
  • 2. Science 316 , 1172, (2007) 摘要
  • Tetrahedron Lett. 25 , 4187, (1984)
  • Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allyl­palladium(II)­ chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)­phosphine, L13329, has been found to give superior results to Palladium(II)­ acetate, 10516, or Tris(d
  • R'kyek, O.; Halland, N. et al. Chem. Eur. J. 16 , 9986, (2010)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Hygroscopic

系列性分类


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