B-Bromocatecholborane B-溴-1,2-苯二酚硼烷

CAS 51901-85-0 MFCD00013341

化学结构图

51901-85-0
SMILES: BrB1OC2C=CC=CC=2O1

化学属性

Mol. FormulaC6H4BBrO2
Mol. Weight198.81
Boiling Point76°C/9mmHg(lit.)
Melting Point51-53 °C(lit.)

别名和识别编码

Chemical NameB-Bromocatecholborane
Synonym B-溴-1,2-苯二酚硼烷 B-溴邻苯二酚硼烷
PubChem Substance ID87565000
Beilstein Registry Number6(4)5612
MDL NumberMFCD00013341
CAS Number51901-85-0
Reaxys-RN2445073
Chemical Name TranslationB-溴-1,2-苯二酚硼烷
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分类

  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Others
  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Other Boronic Acids and Derivatives

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
  • P304+P340+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P301+P330+P331
  • P305+P351+P338
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Hazard Codes C
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Packing GroupIII
Storage condition 0-10 0-10°C
UN Number 2925
Hazard Class4.1/8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Others - Boronic Acids and Derivatives
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Others - Boronic Acids and Derivatives
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Haloboration - C-X Bond Formation (Halogen)

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