2,4-Dichlorophenylboronic acid 2,4-二氯苯硼酸

CAS 68716-47-2 MFCD00013930

化学结构图

68716-47-2
SMILES: OB(O)c1ccc(Cl)cc1Cl

化学属性

Mol. FormulaC6H5BCl2O2
Mol. Weight191
Melting Point242-245 deg. C
TSCANo
Density1.47

别名和识别编码

Chemical Name2,4-Dichlorophenylboronic acid
CAS Number68716-47-2
Alfabeta NameDICHLOROPHENYLBORONICACID 24-,
MDL NumberMFCD00013930
Synonym 2,4-二氯苯硼酸 2,4-二氯苯基硼酸 2,4-Dichlorophenylboronic acid
Beilstein Registry Number4983878
PubChem Substance ID2734659
Reaxys-RN4983878
EC Number000-000-0
Chemical Name Translation2,4-二氯苯硼酸
LabNetwork Molecule IDLN00139895
InChIInChI=1S/C6H5BCl2O2/c8-4-1-2-5(7(10)11)6(9)3-4/h1-3,10-11H
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. X. Zhang, et al., , An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides Synthesis 18 , 2975-2983, (2011)
  • 2. S. Wang, et al., , CuI-catalyzed Suzuki coupling reaction of organoboronic acids with alkynyl bromides Tetrahedron 67 , 4800-4806, (2011)
  • 3. S. Rodriguez-Aristegui, et al., , Versatile synthesis of functionalised dibenzothiophenes via Suzuki coupling and microwave-assisted ring closure Org. Biomolecular Chem. 9 , 6066-6074, (2011)
  • 4. A. D. Chowdhury, et al., , [Pd(L)Cl2]-Catalyzed Selective Hydroxylation of Arylboronic Acids to Phenols Eur. J. Inorg. Chem. 2011 , 3232-3239, (2011)
  • 5. C. Granchi, et al., , N -Hydroxyindole-based inhibitors of lactate dehydrogenase against cancer cell proliferation Eur. J. Med. Chem. 46 , 5398-5407, (2011)
  • 6. X. Huang, et al., , Discovery and Hit-to-Lead Optimization of Non-ATP Competitive MK2 (MAPKAPK2) Inhibitors ACS Med. Chem. Lett. 2 , 632-637, (2011)

安全信息

Warnings IRRITANT, KEEP COLD
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P301+P312
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
GHS Symbol

系列性分类


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