Triphenylbismuth 三苯基铋

CAS 603-33-8 MFCD00014064

化学结构图

603-33-8
SMILES: c1ccc([Bi](c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC18H15Bi
Mol. Weight440.29
Melting Point76-81 °C
Density1.585
SolubilitySlightly soluble in alcohol. Soluble in ether, acetone and chloroform. Insoluble in water
TSCAYes
Boiling Point242 °C at 14 mmHg
Flash Point242°C/14mm
Appearance 本品有毒。眼、皮肤接触引起炎症,食入、吸入有害。操作应穿防护服,戴合成橡胶手套、防毒口罩、防护镜。 运输过程中应防水、防晒、防紫外线辐射。远离强氧化剂。

别名和识别编码

Chemical NameTriphenylbismuth
Synonym Triphenylbismuth {LY} Triphenylbismuth {} {LY} Triphenylbismuth {} {} {LY} Triphenylbismuth {} {} {} {LY} Triphenylbismuth {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylbismuth {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00014064
CAS Number603-33-8
EC Number210-033-4
Reaxys-RN3905930
Beilstein Registry Number16(3)1188
PubChem Substance ID11774
Chemical Name Translation三苯基铋
Wiswesser Line NotationR-BI-R&R
LabNetwork Molecule IDLN00007693
InChIInChI=1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;
Canonical SMILES[Bi](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Bismuth, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors

相关文献及参考

  • Short: III/5b
  • Short: IV/16
  • Short: IV/1a
  • Beilstein:16(3)1188
  • Short: III/20c

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P304+P312
  • P304+P340
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
WGK Germany3
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H332 Harmful if inhaled 吸入有害
RTECSEB2980000
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,317,1952

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01712

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 14,111,1985

其他信息

  • MOL 文件:603-33-8.mol
  • Alfa Aesar:三苯基铋,99+% Triphenylbismuth, 99+%(603-33-8)
  • 图谱信息:三苯基铋(603-33-8)红外图谱(IR1) 三苯基铋(603-33-8)核磁图( 13 CNMR) 三苯基铋(603-33-8)红外图谱(IR2) 三苯基铋(603-33-8)核磁图( 1 HNMR)
  • MSDS 信息:Triphenylbismuth(603-33-8).msds
  • Sigma Aldrich:603-33-8(sigmaaldrich)
  • 三苯基铋价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0511 三苯基泌 Triphenylbismuthine 5G 330元 2014/06/02 T0511 三苯基泌 Triphenylbismuthine 25G 1300元
  • 用途一:优良的高速丁羟推进剂的固化推进剂,应用于国防工业
  • 敏感性:Moisture Sensitive
  • TSCA:Yes

系列性分类


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