3-Methyl-4-nitropyridine 1-oxide 3-甲基-4-硝基吡啶-N-氧化物

CAS 1074-98-2 MFCD00014626

化学结构图

1074-98-2
SMILES: Cc1c[n+]([O-])ccc1[N+](=O)[O-]

化学属性

Mol. FormulaC6H6N2O3
Mol. Weight154.13 g/mol
Melting Point136-138
Density1.36
TSCANo

别名和识别编码

Chemical Name3-Methyl-4-nitropyridine 1-oxide
CAS Number1074-98-2
Alfabeta NameNITROPICOLINEOXIDE N43-----
MDL NumberMFCD00014626
EC Number214-050-8
Beilstein Registry Number0140157
Synonym 3-METHYL-4-NITROPYRIDINE 1-OXIDE 3-METHYL-4-NITROPYRIDINE N-OXIDE 3-METHYL-4-NITROPYRIDINE N-OXIDE 98% 3-Methyl-4-nitropyridine 1-oxide 3-Methyl-4-nitropyridine N-Oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID70633
Reaxys-RN140157
Chemical Name Translation3-甲基-4-硝基吡啶-N-氧化物
Wiswesser Line NotationT6NJ AO C1 DNW
LabNetwork Molecule IDLN00008799
InChIInChI=1S/C6H6N2O3/c1-5-4-7(9)3-2-6(5)8(10)11/h2-4H,1H3
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分类

  • {SNA} NLO Chromophores and Intermediates, Non-Linear Optical (NLO) Materials, Organic and Printed Electronics, Photonic and Optical Materials, 材料科学
  • {SNA} Materials Science, NLO Chromophores and Intermediates, Non-Linear Optical (NLO) Materials, Organic and Printed Electronics, Photonic and Optical Materials

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSUT5775000
Packing GroupIII
UN Number UN2811 2811
Hazard Codes Xn Xn,Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Class6.1
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1680 mg/kg/15W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   70,799,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1680 mg/kg/28W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   62,325,1971

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 500 ug/well
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   32,2369,1972

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - mouse Fibroblast
DOSE/DURATION           : 50 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   35,521,1975

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 nmol/plate
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   70,799,1979

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 500 ug/well
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - hamster Cells - not otherwise specified
DOSE/DURATION           : 8 umol/L
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736)
   V.1-    1869-  Volume(issue)/page/year: 229,416,1971

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 500 umol/L
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   70,799,1979

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其他信息

  • 下游产品:5-氮杂吲哚 --> 4-氯-3-甲基吡啶
  • Sigma Aldrich:1074-98-2(sigmaaldrich)
  • 图谱信息:3-甲基-4-硝基吡啶-N-氧化物(1074-98-2)核磁图( 1 HNMR) 3-甲基-4-硝基吡啶-N-氧化物(1074-98-2)红外图谱(IR1) 3-甲基-4-硝基吡啶-N-氧化物(1074-98-2)核磁图( 13 CNMR) 3-甲基-4-硝基吡啶-N-氧化物(1074-98-2)红外图谱(IR2) 3-甲基-4-硝基吡啶-N-氧化物(1074-98-2)质谱(MS)
  • TCI Shanghai:4-硝基-3-甲基吡啶 N-氧化物 4-Nitro-3-picoline N-Oxide,>;97.0%(T)(1074-98-2)
  • Alfa Aesar:4-硝基-3-甲基吡啶N-氧化物,98% 4-Nitro-3-picoline N-oxide, 98%(1074-98-2)
  • 外观:淡黄色晶体
  • MSDS 信息:3-Methyl-4-nitropyridine-1-oxide(1074-98-2).msds
  • 包装:氟化瓶/铝箔袋/纸板桶
  • MOL 文件:1074-98-2.mol
  • Acros Organics:3-Methyl-4-nitropyridine N-oxide, 98%(1074-98-2)
  • Hazard Note:Irritant/Possible Mutagen
  • 1074-98-2生产厂家:苏州南华生物科技有限公司;天津易创成医药技术有限公司
  • 3-甲基-4-硝基吡啶-N-氧化物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0527 4-硝基-3-甲基吡啶N-氧化物 3-Methyl-4-nitropyridine N-Oxide 5G 1520元 2014/06/02 N0527 4-硝基-3-甲基吡啶N-氧化物 3-Methyl-4-nitropyridine N-Oxide 25G 4790元 2010/06/21 308990050 3-甲基-4-硝基吡啶-N-氧化物 3-Methyl-4-nitropyridine N-oxide 98% 5 GR 1989元

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