CAS 116-11-0 MFCD00014929-2-Methoxypropene 2-甲氧基丙烯 -LabNovo

2-Methoxypropene 2-甲氧基丙烯

CAS 116-11-0 MFCD00014929

化学结构图

SMILES: C=C(C)OC

化学属性

Mol. Formula	C4H8O
Mol. Weight	72
Refractive index	1.3800 to 1.3840
Boiling Point	36°C(lit.)
Density	0.753
Flash Point	-25°C(lit.)
TSCA	Yes
Autoignition Point	374 °F
Vapor Pressure	27.96 psi ( 55 °C)
Solubility	可忽略

别名和识别编码

Chemical Name	2-Methoxypropene
Synonym	1-Propene, 2-methoxy- 2-METHOXYPROPENE 2-METHOXYPROPENE, 99.5+% 2-METHOXYPROPENE, STAB. 2-METHYOXYPROPENE 2-Methoxy-1-propene 2-Methoxypropene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	116-11-0
PubChem Substance ID	8300
EC Number	204-125-3
Beilstein Registry Number	1,435
MDL Number	MFCD00014929
Reaxys-RN	1734635
Chemical Name Translation	2-甲氧基丙烯
Wiswesser Line Notation	1YO1&U1
LabNetwork Molecule ID	LN00192994
InChI	InChI=1S/C4H8O/c1-4(2)5-3/h1H2,2-3H3
Canonical SMILES	C=C(OC)C

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分类

{SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Synthesis, Chromatography, Environmental Standards, Gasoline, Diesel, & Petroleum, M, META - METH, Olefins, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Substance classes, Synthetic Reagents, Volatiles/ Semivolatiles
{uni_hamburg} no charge; ether; 1fragment
Alpha Sort, Alphabetic, Analytical Standards, Analytic
{SNA} Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

安全信息

GHS Symbol

WGK Germany1

Hazard Codes F+,Xn

Hazard statements

H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

RTECSUD0800000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P312+P330
P303+P361+P353
P305+P351+P338
P330 Rinse mouth. 漱口
P370+P378
P403+P235
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word

UN Number 1993

Storage condition 0-10 0-10°C 2-8°C Light Sensitive Store at room temperature, keep dry and cool

Risk Statements

R19 May form explosive peroxides 可能生成易爆的过氧化物质
R12 Extremely flammable 极端易燃
R22 Harmful if swallowed 吞咽有害
R11 Highly flammable 非常易燃

Safety Statements

S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S18 Handle and open container with care 小心搬运和开启容器；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S3 Keep in a cool place 保存在阴凉处；
S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
S29 Do not empty into drains 不要排入下水道；

Packing GroupI

Hazard Class3

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 64000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1870 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

其他信息

2-甲氧基丙烯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 I0303 2-甲氧基丙烯 Isopropenyl Methyl Ether 25ML 180元 2014/06/02 I0303 2-甲氧基丙烯 Isopropenyl Methyl Ether 500ML 1500元 2010/06/21 174350025 2-甲氧基丙烯 2-Methoxypropene 97%, stabilized 2.5 LT 7114元
用途二:2-甲氧基丙烯（116-11-0）是合成克拉霉素（Clarithromycin,简称CLM）的中间体。
TCI Shanghai:2-甲氧基丙烯 Isopropenyl Methyl Ether,>;95.0%(GC)(116-11-0)
储存与运输:2-甲氧基丙烯（116-11-0）爆炸极限为8%-31%，应远离火种密闭、阴景地方保存。运输按第3类第2项易燃液体规定办理。
用途一:用作医药中间体
包装:200升内料四氟乙烯铁桶
Acros Organics:2-甲氧基丙烯 2-Methoxypropene, stabilized, 98%(116-11-0)
Alfa Aesar:2-甲氧基丙烯,98%,stab.withca0.5%potassiumcarbonate 2-Methoxypropene, 98%, stab. with ca 0.5% potassium carbonate(116-11-0)
MSDS 信息:甲基异丙烯基醚(116-11-0).msds
Sigma Aldrich:116-11-0(sigmaaldrich)
2-甲氧基丙烯价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 I0303 2-甲氧基丙烯 Isopropenyl Methyl Ether 25ML 255元 2011/04/16 I0303 2-甲氧基丙烯 Isopropenyl Methyl Ether 500ML 2090元 2010/06/21 174350025 2-甲氧基丙烯 2-Methoxypropene 97%, stabilized 2.5 LT 7114元
蒸气压:27.96 psi ( 55 °C)
外观性质:无色液体。
F:8-10
MOL 文件:116-11-0.mol
图谱信息:2-甲氧基丙烯(116-11-0)核磁图( 13 CNMR) 2-甲氧基丙烯(116-11-0)质谱(MS) 2-甲氧基丙烯(116-11-0)红外图谱(IR2) 2-甲氧基丙烯(116-11-0)核磁图( 1 HNMR) 2-甲氧基丙烯(116-11-0)Raman光谱 2-甲氧基丙烯(116-11-0)红外图谱(IR1)
检测方法:GC
敏感性:Light Sensitive