N,N-Dimethylformamide di-tert-butyl acetal N,N-二甲基甲酰胺二叔丁基缩醛

CAS 36805-97-7 MFCD00015002

化学结构图

36805-97-7
SMILES: CN(C)C(OC(C)(C)C)OC(C)(C)C

化学属性

Mol. Formula(CH3)2NCH[OC(CH3)3]2
Mol. Weight203
Refractive index1.4120 to 1.4150
Boiling Point56-57
Density0.848
Flash Point33°C(lit.)
TSCANo

别名和识别编码

Chemical NameN,N-Dimethylformamide di-tert-butyl acetal
Synonym N,N-DIMETHYLFORMAMIDE DI-T-BUTYL ACETAL N,N-Dimethyl-1,1-bis[(2-methylpropan-2-yl)oxy]methanamine DMF-二特丁基基缩醛 N,N-Dimethylformamide di-tert-butyl acetal, tech. 90%
CAS Number36805-97-7
PubChem Substance ID87567826
EC Number253-222-7
Beilstein Registry Number969629
MDL NumberMFCD00015002
Reaxys-RN969629
Chemical Name TranslationN,N-二甲基甲酰胺二叔丁基缩醛
InChIKeyDBNQIOANXZVWIP-UHFFFAOYSA-N
LabNetwork Molecule IDLN01739685
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Building Blocks, Chemical Synthesis, D, DID - DIN, Orga
  • {SNA} Acetals/Ketals/Ortho Esters, Alkylation Reagents, Amides, Amines, Building Blocks, Chemical Synthesis, DMF-Dialkylacetals, Derivatization Reagents, Derivatization Reagents GC, GC Derivatization Reagents, by Application, Organic Building Blocks, Oxygen Compounds, Reagents for Alkylation & Esterification, Steroids, 分析/色谱, 分析试剂
  • {SNA} Acetals/Ketals/Ortho

相关文献及参考

  • The conversion of carboxylic acids to their esters using DMF acetals (see for example, N,N-Dimethyl­formamide dimethyl­ acetal, A15350) can be extended to the preparation of t-butyl esters by using excess reagent in benzene or toluene as solvent: Synthesis, 135 (1983).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
Signal word
UN Number
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Storage condition Moisture Sensitive
Packing GroupIII
Hazard Class3

其他信息

  • Sigma Aldrich:36805-97-7(sigmaaldrich)
  • MOL 文件:36805-97-7.mol
  • 敏感性:Moisture Sensitive
  • MSDS 信息:1,1-Di-tert-butoxy-N,N-dimethylmethylamine(36805-97-7).msds
  • N,N-二甲基甲酰胺二叔丁基缩醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 5ML 1430元 2014/06/02 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 25ML 4910元 2010/05/25 L00431 N,N-二甲基甲酰胺二叔丁基乙缩醛, tech. 90% N,N-Dimethylformamide di-tert-butyl acetal, tech. 90% 5g 749元
  • F:10-21
  • N,N-二甲基甲酰胺二叔丁基缩醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 5ML 1180元 2011/04/16 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 25ML 4050元 2010/05/25 L00431 N,N-二甲基甲酰胺二叔丁基乙缩醛, tech. 90% N,N-Dimethylformamide di-tert-butyl acetal, tech. 90% 5g 749元
  • Alfa Aesar:N,N-二甲基甲酰胺二叔丁基乙缩醛,tech.90% N,N-Dimethylformamide di-tert-butyl acetal, tech. 90%(36805-97-7)
  • TCI Shanghai:N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification],>;98.0%(N)(36805-97-7)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DID - DIN - D
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Alkylation Reagents - Derivatization Reagents
  5. DMF-Dialkylacetals - Alkylation Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. GC Derivatization Reagents, by Application - Derivatization Reagents GC
  6. Amides - GC Derivatization Reagents, by Application
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Functional Group 官能团索引
  2. orthocarboxylic acid derivative
  1. Functional Group 官能团索引
  2. amide acetal

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