Trioctylphosphine 三辛基膦

CAS 4731-53-7 MFCD00015298

化学结构图

4731-53-7
SMILES: CCCCCCCCP(CCCCCCCC)CCCCCCCC

化学属性

Mol. FormulaC24H51P
Mol. Weight370.65
Refractive index1.4670 to 1.4690
Boiling Point234°C/1mmHg(lit.)
Density0.831 g/mL at 25 °C(lit.)
Flash Point147°C(lit.)
TSCAYes
Stability对空气敏感
Appearance colorless to pale yellow liq.
Melting Point30°C

别名和识别编码

Chemical NameTrioctylphosphine
MDL NumberMFCD00015298
CAS Number4731-53-7
Synonym Tri-n-octylphosphine,min.97%TOP TRIOCTYLPHOSPHINE NSC 102529 tl411 CYTOP(R) 380 三正辛基膦 TRI-N-OCTYLPHOSPHINE TL 411 nsc102529 Tri-n-octylphosphine Tri-n-octylphosphine, Technical Grade, 90% Cytop® 380 P(Oct)3 Cytop? 380 三正辛基膦, TECH HISHICOLIN P-8 三辛基膦 trioctyl-phosphin P(Oct)3 TOP P(Oct)3 Tri-n-octylphosphine, TOP,min. 97% TRIOCTYLPHOSPHINE (CYTOP 380) CYTEC QUALITY TRIOCTYLPHOSPHINE (TOCP) Trisoctylphosphine Trioctylphosphine TRIOCTYLPHOSPHINE, TECH., 90% TRI-N-OCTYLPHOSPHINE (TOP) Tri-n-octylphosphine, tech., 90% Tri-n-octylphosphine,tech.90%
PubChem Substance ID87576433
EC Number225-234-2
Beilstein Registry Number1776995
Reaxys-RN1776995
Chemical Name Translation三辛基膦
InChIKeyRMZAYIKUYWXQPB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225375
InChIInChI=1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
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分类

  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • {SNA} 25mL Sure/Seal Reagents, Catalysis and Inorganic Chemistry, Chemical Synthesis, Organometallic Reagents, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Beilstein: 4,IV,3438

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H302+H312+H332
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSZ3450000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P303+P361+P353
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P304+P340+P310
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P330+P331+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Packing GroupII
UN Number 1760 UN 1760 8/PG 2 UN1760
Risk Statements
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition 充氩储存 对空气敏感，密封保存。 Air Sensitive
Hazard Codes C
Hazard Class8 
TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1600 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,DEC1942

其他信息

  • Alfa Aesar:三正辛基膦,tech.90% Tri-n-octylphosphine, tech. 90%(4731-53-7)
  • 检测方法:GC
  • 图谱信息:三辛基膦(4731-53-7)核磁图( 1 HNMR) 三辛基膦(4731-53-7)红外图谱(IR1) 三辛基膦(4731-53-7)核磁图( 13 CNMR) 三辛基膦(4731-53-7)质谱(MS)
  • 敏感性:Air Sensitive
  • Sigma Aldrich:4731-53-7(sigmaaldrich)
  • F:10-13-23
  • MOL 文件:4731-53-7.mol
  • TCI Shanghai:三正辛基膦 Tri-n-octylphosphine,>;85.0%(GC)(4731-53-7)
  • 三辛基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A11785402 三辛基膦 100ml 1855元 2011/08/23 K9284001 三辛基膦 100ml 1759元 2011/04/16 T0503 三正辛基膦 Tri-n-octylphosphine 500ML 4100元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Mitsunobu Reaction
  1. Functional Group 官能团索引
  2. phosphine
  1. Nanomaterials
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Surfactants for Nano Synthesis
  2. Phosphorus
  1. Ligands
  2. Phosphorus