Dicyclopropylmethanol 二环丙基甲醇
CAS 14300-33-5 MFCD00019249
化学结构图
SMILES: OC(C1CC1)C1CC1
化学属性
| Mol. Formula | C7H12O |
|---|---|
| Mol. Weight | 112.17 |
| Refractive index | 1.4650 |
| Flash Point | >110°(230°F) |
| TSCA | No |
| Boiling Point | 99-100°/12mm |
| Density | 0.951 g/mL at 20 °C(lit.) |
别名和识别编码
| Chemical Name | Dicyclopropylmethanol |
|---|---|
| MDL Number | MFCD00019249 |
| Synonym | Dicyclopropyl carbinol |
| EC Number | 238-236-3 |
| CAS Number | 14300-33-5 |
| Beilstein Registry Number | 2203215 |
| PubChem Substance ID | 329778337 |
| Chemical Name Translation | 二环丙基甲醇 |
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分类
- {SNA} Alcohols, Building Blocks, C7 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Esters of this alcohol undergo extremely rapid solvolysis under mildly acidic conditions such as 1% TFA in dichloromethane. This is due to the effective stabilization of a cation ɑAlpha/D to the cyclopropyl group. Carpino has shown that the dicyclopropylmethyl (Dcpm) group is therefore a potentially very useful, low molecular weight protecting group for the carboxyl function, particularly in peptide synthesis; selective removal in the presence of such acid-sensitive groups as t-butyl, N-Trt, etc. can be achieved: J. Org. Chem., 60, 7718 (1995). See Appendix 6.
安全信息
Precautionary statements
- P305+P351+P338
Hazard statements
- H319 Causes serious eye irritation 严重刺激眼睛
WGK Germany3
Signal word
Warning
GHS Symbol
Personal Protective Equipment
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
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