3-VINYL-7-OXABICYCLO(4.1.0)HEPTANE 1,2-环氧-4-乙烯基环己烷(异构体混合物)

CAS 106-86-5 MFCD00022356

化学结构图

106-86-5
SMILES: C=C[C@H]1CC[C@@H]2O[C@H]2C1

化学属性

Mol. FormulaC8H12O
Mol. Weight124.18
Density0.952
Refractive index1.4680 to 1.4720
Boiling Point169°C at 760 mmHg
Flash Point46°C
Melting Point-100°C
Solubility不溶于水。

别名和识别编码

Chemical Name3-VINYL-7-OXABICYCLO(4.1.0)HEPTANE
MDL NumberMFCD00022356
CAS Number106-86-5
EC Number203-436-1
Beilstein Registry Number0107390
Synonym 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isom
PubChem Substance ID7832
Chemical Name Translation1,2-环氧-4-乙烯基环己烷(异构体混合物)
Reaxys-RN107390
Wiswesser Line NotationT36 BOTJ E1U1
InChIKeySLJFKNONPLNAPF-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222099
InChIInChI=1S/C8H12O/c1-2-6-3-4-7-8(5-6)9-7/h2,6-8H,1,3-5H2
Canonical SMILESC=CC1CC2OC2CC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; large ring; fused rings; 3ring; 6ring; 7ring; ether; 1fragment
  • {SNA} Materials Science, Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • {SNA} Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学

相关文献及参考

  • Beilstein: 17,IV,314
  • Short: EINECS
  • Short: III/38B

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P303+P361+P353
  • P305+P351+P338
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P337+P313
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRN8770000
Hazard Codes
UN Number
Packing GroupIII
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -
Hazard Class3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 6/11/1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2830 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 6/11/1963

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 12 gm/kg
SEX/DURATION            : male 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - other effects on male
REFERENCE :
   TOXID9 Toxicologist.  (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway,
   Akron, OH 44311) V.1-    1981-  Volume(issue)/page/year: 12,435,1992

其他信息

  • 外观性质:无色不稳定液体。
  • MSDS 信息:1,2-环氧-4-乙烯基环己烷(106-86-5).msds
  • 包装:镀锌铁桶，净重180Kg，桶重21Kg左右。
  • 贮存:贮存于阴凉通风处，远离火源、热源。
  • 性质特征:106-86-5（1,2-环氧-4-乙烯基环己烷）为无色透明液体，有轻微刺激性气味，比重0.952，沸点169℃，无毒，易燃，1,2-环氧-4-乙烯基环己烷可发生加成、聚合等化学反应，广泛应用于发光材料、电子芯片封装剂、胶粘剂、偶联剂、有机硅合成、微电子等行业和领域。
  • Sigma Aldrich:106-86-5(sigmaaldrich)
  • MOL 文件:106-86-5.mol

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Vinyl Halides, Amines, Amides, and Other Vinyl Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds

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