Phenyltrimethoxysilane 苯基三甲氧基硅烷

CAS 2996-92-1 MFCD00025689

化学结构图

2996-92-1
SMILES: CO[Si](OC)(OC)c1ccccc1

化学属性

Mol. FormulaC9H14O3Si
Mol. Weight198.29
Refractive index1.4720 to 1.4750
Boiling Point233
Density1.062
Flash Point94°C(lit.)
TSCAYes
Melting Point-25
Stability对湿度敏感
Appearance 苯基三甲氧基硅烷(2996-92-1)为无色透明液体, 熔点 -25°C ，沸点 233 ;°C ，密度 1.062 ;g/mL ;at 25 ;°C ，折光率 n 20/D 1.468 ，闪点 99 ;°F.可溶于有机溶剂，不溶于水。

别名和识别编码

Chemical NamePhenyltrimethoxysilane
Synonym Trimethoxy(phenyl)silane {LY} Trimethoxy(phenyl)silane Trimethoxyphenylsilane {} {LY} Trimethoxy(phenyl)silane {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00025689
CAS Number2996-92-1
PubChem Substance ID18137
EC Number221-066-9
Beilstein Registry Number2937896
Reaxys-RN2937896
Chemical Name Translation苯基三甲氧基硅烷
Wiswesser Line Notation1O-SI-R&O1&O1
LabNetwork Molecule IDLN00197897
InChIInChI=1S/C9H14O3Si/c1-10-13(11-2,12-3)9-7-5-4-6-8-9/h4-8H,1-3H3
Canonical SMILESCO[Si](C1=CC=CC=C1)(OC)OC
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分类

  • {SNA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Silanes, Silicon, Solution Deposition Precursors, Trialkoxysilanes
  • {SNA} Chemical Synthesis, Micro/NanoElectronics, Nanomaterials, Organometallic Reagents, Organosilicon, POSS Precursors and Intermediates, RSi(OR″)3, Self Assembly and Lithography, Self-Assembly Materials, Silanes, Silsesquioxanes: POSS Nanohybrids, Trialkoxysilanes, 材料科学
  • {SNA} Chemical Synthesis, Micro/NanoElectronics, Organometallic Reagents, Organosilic

相关文献及参考

  • Aryltrimethoxysilanes undergo Pd-catalyzed cross-coupling reactions with e.g. aryl iodides in the presence of TBAF, via a postulated hypervalent siloxane intermediate: J. Org. Chem., 64, 1684 (1999):
  • Beilstein: 16,IV,1556
  • Short: EINECS
  • Short: IV/18A

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H371 May cause damage to organs 可能导致器官损伤
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV5252000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P330 Rinse mouth. 漱口
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
Signal word Danger Warning
Risk Statements
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R68/20/21/22
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes T,Xi,Xn Xn Xi
UN Number UN 1992 3/PG 3 1993
Packing GroupIII
Hazard Class3.2 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04066

其他信息

  • Alfa Aesar:苯基三甲氧基硅烷,97% Phenyltrimethoxysilane, 97%(2996-92-1)
  • 图谱信息:苯基三甲氧基硅烷(2996-92-1)红外图谱(IR1) 苯基三甲氧基硅烷(2996-92-1)核磁图( 13 CNMR) 苯基三甲氧基硅烷(2996-92-1)核磁图( 1 HNMR) 苯基三甲氧基硅烷(2996-92-1)质谱(MS)
  • TCI Shanghai:三甲氧基苯基硅烷 Trimethoxyphenylsilane,>;98.0%(GC)(2996-92-1)
  • 苯基三甲氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0857 三甲氧基苯基硅烷 Trimethoxyphenylsilane 25ML 133元 2014/06/02 P0857 三甲氧基苯基硅烷 Trimethoxyphenylsilane 500ML 1050元 2010/06/21 370640500 苯基三甲氧基硅烷 Phenyltrimethoxysilane 85% 50 ML 121元
  • F:10-21
  • 存储注意事项:湿度敏感
  • MOL 文件:2996-92-1.mol
  • Sigma Aldrich:2996-92-1(sigmaaldrich)
  • Acros Organics:苯基三甲氧基硅烷 Phenyltrimethoxysilane, 85%(2996-92-1)
  • 敏感性:Moisture Sensitive
  • 用途一:用作制备高分子有机硅化合物的原料
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Trialkoxysilanes - Organosilicon
  1. Materials Science 材料科学
  2. Nanomaterials - Materials Science
  3. Silsesquioxanes: POSS® Nanohybrids - Nanomaterials
  4. POSS® Precursors and Intermediates - Silsesquioxanes: POSS® Nanohybrids
  5. RSi(OR″)3 - POSS® Precursors and Intermediates
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Silicon - Solution Deposition Precursors
  5. Silanes 硅烷

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