(4-Methoxybenzyl)triphenylphosphonium chloride (4-甲氧基苄基)三苯基氯化膦

CAS 3462-97-3 MFCD00031572

化学结构图

3462-97-3
SMILES: [Cl-].COC1C=CC(C[P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1

化学属性

Mol. FormulaC26H24ClOP
Mol. Weight418.90
Melting Point236-238 °C
TSCANo

别名和识别编码

Chemical Name(4-Methoxybenzyl)triphenylphosphonium chloride
MDL NumberMFCD00031572
CAS Number3462-97-3
Beilstein Registry Number4173378
Chemical Name Translation(4-甲氧基苄基)三苯基氯化膦
Synonym (4-Methoxybenzyl)triphenylphosphonium chloride {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium
LabNetwork Molecule IDLN01305631
Canonical SMILESCOC1=CC=C(C[P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)C=C1.[Cl-]
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相关文献及参考

  • Benzylic phosphonium salts undergo the Wittig reaction with aromatic aldehydes using solid KOH in the presence of 18-crown-6 to give (Z)-stilbenes with good stereoselectivity: Tetrahedron Lett., 37, 4225 (1996). See Appendix 1.

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition

其他信息

  • MOL 文件:3462-97-3.mol
  • Acros Organics:(4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphoniumchloride,98%(3462-97-3)
  • (4-甲氧基苄基)三苯基氯化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 376320250 (4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphonium chloride 98% 25 GR 2103元 2010/06/21 376321000 (4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphonium chloride 98% 100 GR 5932元 2010/06/21 376320050 (4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphonium chloride 98% 5 GR 654元
  • Sigma Aldrich:3462-97-3(sigmaaldrich)
  • Alfa Aesar:(4-甲氧基苄基)三苯基氯化膦,97% (4-Methoxybenzyl)triphenylphosphonium chloride, 97%(3462-97-3)

系列性分类


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