Diphenyliodonium bromide 溴化二苯基碘

CAS 1483-73-4 MFCD00031703

化学结构图

1483-73-4
SMILES: [Br-].c1ccc([I+]c2ccccc2)cc1

化学属性

Mol. FormulaC12H10BrI
Mol. Weight361.02
Melting Point222.5-227.5 °C
TSCAYes

别名和识别编码

Chemical NameDiphenyliodonium Bromide
Synonym Diphenyliodonium bromide {LY} Diphenyliodonium bromide diphenyliodonium diphenyliodonium bromide diphenyliodonium chloride diphenyliodonium hexafluoroarsenate diphenyliodonium hexafluorophosphate diphenyliodonium iodide diphenyliodonium nitrate diphenyliodonium nitrite diphenyliodonium sulfate (1:1) diphenyliodonium tosylate iodonium biphenyl iodoniumdiphenyl {} {LY} Diphenyliodonium bromide {} {} {LY} Diphenyliodonium bromide {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {} {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {} {} {} {} {} {LY} Diphenyliodonium bromide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Diphenyliodoniu
MDL NumberMFCD00031703
CAS Number1483-73-4
EC Number216-050-3
Beilstein Registry Number5(4)692
PubChem Substance ID73871
Reaxys-RN3918437
Chemical Name Translation溴化二苯基碘
InChIKeyLGPSGXJFQQZYMS-UHFFFAOYSA-M
LabNetwork Molecule IDLN01741803
InChIInChI=1S/C12H10I.BrH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
Canonical SMILESC1=CC=C(C=C1)[I+]C2=CC=CC=C2.[Br-]
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic

相关文献及参考

  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/20c Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zr ... Bi. Diagrams, Structure formulas, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20c Year: 1989 Keyword: NQR ISBN: 3-540-18490-2 ISBN: 978-3-540-18490-4 Internet Resource: DOI:10.1007/b35374 RefComment: 562 figs., IX,802 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zn ... Bi. Diagrams, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31b Year: 1993 Keyword: NQR ISBN: 3-540-55147-6 ISBN: 978-3-540-55147-8 Internet Resource: DOI:10.1007/b4609

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Packing GroupIII
UN Number 2811
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301 IF SWALLOWED: 如果吞下去
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Class6.1
GHS Symbol
Hazard Codes T

其他信息

  • Acros Organics:Diphenyliodonium bromide, 98%(1483-73-4)
  • TCI Shanghai:二苯基溴化碘 Diphenyliodonium Bromide,>;98.0%(T)(1483-73-4)
  • 二苯基溴化碘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2372 二苯基溴化碘 Diphenyliodonium Bromide 5G 1110元 2010/06/21 408950050 二苯基溴化碘 Diphenyliodonium bromide 98% 5 GR 771元 2010/06/21 408950250 二苯基溴化碘 Diphenyliodonium bromide 98% 25 GR 2867元
  • Alfa Aesar:二苯基二溴化碘,98% Diphenyliodonium bromide, 98%(1483-73-4)
  • MOL 文件:1483-73-4.mol
  • Sigma Aldrich:1483-73-4(sigmaaldrich)
  • 图谱信息:二苯基溴化碘(1483-73-4)红外图谱(IR1) 二苯基溴化碘(1483-73-4)质谱(MS) 二苯基溴化碘(1483-73-4)红外图谱(IR2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Hypervalent Iodine - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Hypervalent Iodine Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Iodonium, Sulfonium & Oxonium Compounds

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