N-Bromoacetamide N-溴代乙酰胺

CAS 79-15-2 MFCD00037097

化学结构图

79-15-2
SMILES: CC(=O)NBr

化学属性

Mol. FormulaC2H4BrNO
Mol. Weight137.96
Melting Point102-106 °C
TSCAYes
Appearance 白色粉末。熔点108℃。溶于热水，易溶于乙醚。遇光和热不稳定。一水合物熔点70-80℃，溶于冷水、乙醚、乙醇，微溶于氯仿。 powder
Boiling Point127-130 °C at 16 mmHg

别名和识别编码

Chemical NameN-Bromoacetamide
Synonym N-Bromoacetamide {LY} N-Bromoacetamide {} {LY} N-Bromoacetamide {} {} {LY} N-Bromoacetamide {} {} {} {LY} N-Bromoacetamide {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Bromoacetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number2,181
PubChem Substance ID4353
CAS Number79-15-2
EC Number201-181-0
MDL NumberMFCD00037097
Reaxys-RN969346
Merck Number1398
Chemical Name TranslationN-溴代乙酰胺
InChIInChI=1S/C2H4BrNO/c1-2(5)4-3/h1H3,(H,4,5)
Canonical SMILESCC(NBr)=O
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分类

  • Analytical Standards, Analytical/Chromatography, Biochemicals and Reagents, Chromatography, D to K, Environmental Standards, Enzyme Inhibitors,
  • {SNA} Analytical Standards, Analytical/Chromatography, Biochemicals and Reagents, Chromatography, D to K, Environmen
  • {SN

相关文献及参考

  • Merck 14 ,1398
  • Source of positive bromine, useful for the conversion of alkenes to bromohydrins under mild conditions: Helv. Chim. Acta, 26, 562, 746, 1799 (1943); Tetrahedron Lett., 765 (1973). It is also a useful reagent for mild oxidation of secondary alcohols to ketones: J. Biol. Chem., 184, 393 (1950); J. Am. Chem. Soc., 76, 3682 (1954); 85, 1409 (1963).
  • In combination with AgOAc and AcOH, has been used to convert alkenes stereoselectively to cis-1,2-diols: Tetrahedron Lett., 1581 (1976).

安全信息

Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Hazard Codes Xi
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
UN Number 1759 3261 UN3261
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Packing GroupIII
Hazard Class8

其他信息

  • 用途一:用于有机合成。作溴化剂，氧化剂，催化剂。
  • TCI Shanghai:N-溴代乙酰胺 N-Bromoacetamide,>;97.0%(T)(79-15-2)
  • F:8
  • Alfa Aesar:N-溴乙酰胺,95% N-Bromoacetamide, 95%(79-15-2)
  • MOL 文件:79-15-2.mol
  • 图谱信息:N-溴代乙酰胺(79-15-2)红外图谱(IR3) N-溴代乙酰胺(79-15-2)核磁图( 13 CNMR) N-溴代乙酰胺(79-15-2)红外图谱(IR1) N-溴代乙酰胺(79-15-2)质谱(MS) N-溴代乙酰胺(79-15-2)红外图谱(IR2)
  • color:white to yellow
  • Sigma Aldrich:79-15-2(sigmaaldrich)
  • N-溴代乙酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0530 N-溴代乙酰胺 N-Bromoacetamide 5G 350元 2014/06/02 B0530 N-溴代乙酰胺 N-Bromoacetamide 25G 750元 2010/05/25 L02953 N-溴乙酰胺, 95% N-Bromoacetamide, 95% 5g 818元
  • 方法一:由乙酰胺与溴反应而得。将乙酰胺溶于摩尔的液溴中，在冷却至4-5℃后，搅拌下加入预冷的氢氧化钾溶液。生成半固体物在0-5℃放置2-3h。在反应混合物中加氯化钠、氯仿，搅拌加热后，将氯仿溶液从固体物质中倾出，用氯仿再萃取两次。将萃取液加无水硫酸钠干燥，过滤。加入乙烷使结晶析出，冷却，过滤，用己烷洗涤，干燥即得N-溴乙酰胺。产率约50%。
  • 上游原料:氢氧化钾溶液 --> 液溴

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Molluscicides - Pesticides
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Enzyme Inhibitors - Enzymes, Inhibitors, and Substrates
  5. Enzyme Inhibitors by Enzyme - Enzyme Inhibitors
  6. D to K - Enzyme Inhibitors by Enzyme
  7. Fusarinine -C Ornithinesterase - D to K

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