2,2,4-Trimethyl-6-Keto-1,3-Dioxin 2,2,6-三甲基-4H-1,3-二噁英-4-酮
CAS 5394-63-8 MFCD00040468
化学结构图
SMILES: CC1=CC(=O)OC(C)(C)O1
化学属性
| Mol. Formula | C7H10O3 |
|---|---|
| Mol. Weight | 142.15 |
| Density | 1.07 |
| Refractive index | n20/D 1.460(lit.) |
| Boiling Point | 275 °C at 760 mmHg |
| Melting Point | 12-13 °C |
| Flash Point | 86°C(lit.) |
| TSCA | No |
| Solubility | 难溶 |
别名和识别编码
| Chemical Name | 2,2,4-Trimethyl-6-Keto-1,3-Dioxin |
|---|---|
| Synonym | 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3-dioxin-4-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2,6-Trimethyl-4H-1,3- |
| CAS Number | 5394-63-8 |
| Beilstein Registry Number | 2408 |
| MDL Number | MFCD00040468 |
| EC Number | 211-339-0 |
| Reaxys-RN | 2408 |
| PubChem Substance ID | 79368 |
| Chemical Name Translation | 2,2,6-三甲基-4H-1,3-二噁英-4-酮 |
| InChIKey | XFRBXZCBOYNMJP-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01306716 |
| InChI | InChI=1S/C7H10O3/c1-5-4-6(8)10-7(2,3)9-5/h4H,1-3H3 |
| Canonical SMILES | O=C1OC(C)(C)OC(C)=C1 |
信息真实价格透明
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Lactones, Organic Building Blocks
- {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Other Heterocyclic Building Blocks
- Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Others
产品应用
- Usually used in the synthesis of acetylketene by flash pyrolysis.
相关文献及参考
- Beilstein:19(3/4)1604
- Convenient alternative to diketene in many reactions, stable in the absence of base: J. Am. Chem. Soc., 75, 5400 (1953).
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H227 Combustible liquid 可燃液体
- H319 Causes serious eye irritation 严重刺激眼睛
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R11 Highly flammable 非常易燃
- R36 Irritating to eyes 刺激眼睛
其他信息
- 不溶于水，溶于丙酮和乙醇。
- Sigma Aldrich:5394-63-8(sigmaaldrich)
- 海关编码:29329995
- MSDS 信息:2,2,6-Trimethyl-4H-1,3-dioxin-4-one(5394-63-8).msds
- Acros Organics:2，2，6-三甲基-4H-1,3-二氧环辛烯-4-酮 2,2,6-Trimethyl-4H-1,3-dioxin-4-one, 90-95%(5394-63-8)
- TCI Shanghai:2,2,6-三甲基-1,3-二氧杂环已烯-4-酮 2,2,6-Trimethyl-1,3-dioxin-4-one,>;90.0%(GC)(5394-63-8)
- Alfa Aesar:2,2,6-三甲基-1,3-二氧(杂)芑-酮,94%,cont.uptoca6%乙酮 2,2,6-Trimethyl-1,3-dioxin-4-one, 94%, cont. up to ca 6% acetone(5394-63-8)
- MOL 文件:5394-63-8.mol
- 2,2,6-三甲基-4H-1,3-二英-4-酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1099 2,2,6-三甲基-1,3-二恶英-4-酮 2,2,6-Trimethyl-1,3-dioxin-4-one 25ML 279元 2014/06/02 T1099 2,2,6-三甲基-1,3-二恶英-4-酮 2,2,6-Trimethyl-1,3-dioxin-4-one 500ML 1250元 2010/06/21 296910050 2,2,6-三甲基-4H-1,3-二英-4-酮 2,2,6-Trimethyl-4H-1,3-dioxin-4-one 90-95% 5 GR 456元
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