(4-Chlorobenzyl)Triphenylphosphonium Chloride 4-(氯苄基)三苯基氯化磷鎓盐

CAS 1530-39-8 MFCD00041533

化学结构图

1530-39-8
SMILES: Clc1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1.[Cl-]

化学属性

Mol. FormulaC25H21Cl2P
Mol. Weight423.31
Melting Point>300 °C
TSCANo

别名和识别编码

Chemical Name(4-Chlorobenzyl)Triphenylphosphonium Chloride
Synonym (4-Chlorobenzyl)triphenylphosphonium chloride {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Chlorobenzyl)triph
MDL NumberMFCD00041533
PubChem Substance ID2733546
CAS Number1530-39-8
EC Number216-228-0
Reaxys-RN4173400
Beilstein Registry Number4173400
Chemical Name Translation4-(氯苄基)三苯基氯化磷鎓盐
InChIKeyRAHOAHBOOHXRDY-UHFFFAOYSA-M
LabNetwork Molecule IDLN01741173
InChIInChI=1S/C25H21ClP.ClH/c26-22-18-16-21(17-19-22)20-27(23-10-4-1-5-11-23,24-12-6-2-7-13-24)25-14-8-3-9-15-25;/h1-19H,20H2;1H/q+1;/p-1
Canonical SMILESC1=CC=C(C=C1)[P+](CC2=CC=C(C=C2)Cl)(C3=CC=CC=C3)C4=CC=CC=C4.[Cl-]
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 2. E. Luethi, et al., J. Med. Chem. 53 , 7236-7250, (2010)
  • 3. F. O. Silverio, et al., Pest Mgmt Sci. 65 , 900-905, (2009)
  • 4. P. A. Castelo-Branco, et al., Pest Mgmt Sci. 65 , 34-40, (2009)
  • 1. M. Cui, et al., Eur. J. Med. Chem. 46 , 2908-2916, (2011)
  • 7. A. Sandulache, et al., New J. Chem. 27 , 1592-1598, (2003)
  • 6. G. Aguirre, et al., Bioorg. Med. Chem. 13 , 6336-6346, (2005)
  • FT-IR 2 (2), 3335:C / Structure Index 1 , 356:C:6
  • 5. W. Porcal, et al., Org. Process Res. Dev. 12 , 156-162, (2008)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:1530-39-8.mol
  • TCI Shanghai:4-氯苄基三苯基氯化磷盐 (4-Chlorobenzyl)triphenylphosphonium Chloride,>;97.0%(T)(1530-39-8)
  • Sigma Aldrich:1530-39-8(sigmaaldrich)
  • 4-氯苄基三苯基氯化磷蓊盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1581 4-(氯苄基)三苯基氯化磷盐 (4-Chlorobenzyl)triphenylphosphonium Chloride 5G 292元 2014/06/02 C1581 4-(氯苄基)三苯基氯化磷盐 (4-Chlorobenzyl)triphenylphosphonium Chloride 25G 883元 2010/05/25 A11769 （4－氯苄基）三苯基氯化磷, 98+% (4-Chlorobenzyl)triphenylphosphonium chloride, 98+% 25g 1088元
  • 敏感性:Hygroscopic
  • Alfa Aesar:（4－氯苄基）三苯基氯化磷,98+% (4-Chlorobenzyl)triphenylphosphonium chloride, 98+%(1530-39-8)
  • 图谱信息:4-氯苄基三苯基氯化磷蓊盐(1530-39-8)核磁图( 13 CNMR) 4-氯苄基三苯基氯化磷蓊盐(1530-39-8)质谱(MS) 4-氯苄基三苯基氯化磷蓊盐(1530-39-8)核磁图( 1 HNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Alcohols - Chemical Class
  5. Aromatic - Alcohols
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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